Calibration-free analysis of TC4 titanium alloy using high-repetition-rate fiber laser-induced breakdown spectroscopy

ZHU Fangyin; LIN Ruitao; WANG Bin; JIANG Erlong; ZHAO Nan; ZHOU Wenwen; ZHENG Shaofeng; LI Jiaming; ZHANG Qingmao

doi:10.37188/OPE.20253319.3032

您当前的位置：

首页 >

文章列表页 >

Calibration-free analysis of TC4 titanium alloy using high-repetition-rate fiber laser-induced breakdown spectroscopy

Modern Applied Optics | 更新时间：2025-11-03

- Calibration-free analysis of TC4 titanium alloy using high-repetition-rate fiber laser-induced breakdown spectroscopy
- Optics and Precision Engineering Vol. 33, Issue 19, Pages: 3032-3042(2025)
- 作者机构：
  
  1.华南师范大学光电科学与工程学院，广东广州 510006
  2.广东技术师范大学电子与信息学院，广东广州 510665
  3.广东省口岸安全智能化检测重点实验室黄埔海关技术中心，广东广州 510510
  4.莱森光学（深圳）有限公司，广东深圳 518101
- 作者简介：
- 基金信息：
- DOI：10.37188/OPE.20253319.3032
  CLC： O657.3
- CSTR：32169.14.OPE.20253319.3032
- Received：31 July 2025，
  
  Revised：2025-08-13，
  
  Published：10 October 2025
- 稿件说明：
移动端阅览
朱方印,林锐涛,王斌等.高重频光纤激光诱导击穿光谱对TC4钛合金的免定标分析[J].光学精密工程,2025,33(19):3032-3042.

ZHU Fangyin,LIN Ruitao,WANG Bin,et al.Calibration-free analysis of TC4 titanium alloy using high-repetition-rate fiber laser-induced breakdown spectroscopy[J].Optics and Precision Engineering,2025,33(19):3032-3042.
朱方印,林锐涛,王斌等.高重频光纤激光诱导击穿光谱对TC4钛合金的免定标分析[J].光学精密工程,2025,33(19):3032-3042. DOI： 10.37188/OPE.20253319.3032. CSTR： 32169.14.OPE.20253319.3032.

ZHU Fangyin,LIN Ruitao,WANG Bin,et al.Calibration-free analysis of TC4 titanium alloy using high-repetition-rate fiber laser-induced breakdown spectroscopy[J].Optics and Precision Engineering,2025,33(19):3032-3042. DOI： 10.37188/OPE.20253319.3032. CSTR： 32169.14.OPE.20253319.3032.

摘要

传统激光诱导击穿光谱（Laser-Induced Breakdown Spectroscopy， LIBS）采用的低重频固体激光器存在长时间连续工作稳定性不足的问题。光纤激光诱导击穿光谱（Fiber Laser-Induced Breakdown Spectroscopy， FL-LIBS）虽然可以提供更高的长期稳定性，但其重复频率过高，因此，目前皆用时间积分光谱结合参考样品定标曲线法定量分析研究。为摆脱参考样品的限制，本文在FL-LIBS平台上构建了高速高重频触发门控系统，实现了等离子体瞬态光谱的采集，开发出免定标定量分析算法，并改进内部参考线法（Internal Reference Self-absorption Correction， IRSAC）进行光谱自吸收校正，进一步提高了免定标定量分析的准确度。实验结果表明，TC4钛合金总体分析误差（Distance Error， DE）为 0.883%~3.928%（质量分数），相比未校正自吸收效应减少16.879%~26.597%（质量分数）。这证明了该方法可以在高重频光纤激光烧蚀的条件下实现高准确度的免定标定量分析，为长时间连续工作的LIBS系统提供了解决方案。

Abstract

Traditional laser-induced breakdown spectroscopy （LIBS） employing low-repetition-rate solid-state lasers exhibits insufficient stability during extended continuous operation. Although fiber-laser-induced breakdown spectroscopy （FL-LIBS） offers superior long-term stability， its high repetition rate poses challenges for conventional quantitative approaches， which typically rely on time-integrated spectra and calibration with reference samples. To remove dependence on reference standards， a high-speed， high-repetition-frequency triggered-gating system was implemented on an FL-LIBS platform to capture transient plasma spectra. A calibration-free quantitative analysis algorithm was developed， and the Internal Reference Self-absorption Correction （IRSAC） method was improved to compensate for spectral self-absorption， thereby enhancing the accuracy of calibration-free quantification. Experimental results for TC4 titanium alloy indicate total analysis distance errors （DE） ranging from 0.883% to 3.928%（mass fraction）， corresponding to reductions of 16.879% to 26.597 %（mass fraction） relative to uncorrected self-absorption. These findings demonstrate that high-accuracy calibration-free quantitative analysis can be achieved under high-repetition-frequency fiber laser ablation， offering a viable approach for LIBS systems that require prolonged continuous operation.

关键词

Keywords

references

KANG C D ， ZHANG Y Y ， ZHANG M Y ， et al . Screening of specific quantitative peptides of beef by LC-MS/MS coupled with OPLS-DA ［J］. Food Chemistry ， 2022 ， 387 ： 132932 . doi: 10.1016/j.foodchem.2022.132932 http://dx.doi.org/10.1016/j.foodchem.2022.132932

KOVTUN A ， JONES D ， DELL’ELCE S ， et al . Accurate chemical analysis of oxygenated graphene-based materials using X-ray photoelectron spectroscopy ［J］. Carbon ， 2019 ， 143 ： 268 - 275 . doi: 10.1016/j.carbon.2018.11.012 http://dx.doi.org/10.1016/j.carbon.2018.11.012

GOMEZ A ， SAINBHI A S ， FROESE L ， et al . The quantitative associations between near infrared spectroscopic cerebrovascular metrics and cerebral blood flow： a scoping review of the human and animal literature ［J］. Frontiers in Physiology ， 2022 ， 13 ： 934731 . doi: 10.3389/fphys.2022.934731 http://dx.doi.org/10.3389/fphys.2022.934731

ABDULHUSSEIN N M ， MUSLIM N M ， HUSSIEN M A ， et al . Green preconcentration procedures for the determination of aluminium in bottled beverages prior to electrothermal atomic absorption spectroscopy： a comparative study with environmental assessment tools ［J］. Journal of the Iranian Chemical Society ， 2024 ， 21 （ 5 ）： 1203 - 1212 . doi: 10.1007/s13738-024-02979-y http://dx.doi.org/10.1007/s13738-024-02979-y

HAI R ， WANG X Y ， BAI X ， et al . Analysis of an Al-Sn-Cu alloy by calibration-free laser-induced breakdown spectroscopy under varying sample temperature conditions ［J］. Spectrochimica Acta Part B： Atomic Spectroscopy ， 2024 ， 217 ： 106976 . doi: 10.1016/j.sab.2024.106976 http://dx.doi.org/10.1016/j.sab.2024.106976

HAHN D W ， OMENETTO N . Laser-induced breakdown spectroscopy （LIBS）， part II： review of instrumental and methodological approaches to material analysis and applications to different fields ［J］. Applied Spectroscopy ， 2012 ， 66 （ 4 ）： 347 - 419 . doi: 10.1366/11-06574 http://dx.doi.org/10.1366/11-06574

NOLL R ， FRICKE-BEGEMANN C ， CONNEMANN S ， et al . LIBS analyses for industrial applications-an overview of developments from 2014 to 2018 ［J］. Journal of Analytical Atomic Spectrometry ， 2018 ， 33 （ 6 ）： 945 - 956 . doi: 10.1039/c8ja00076j http://dx.doi.org/10.1039/c8ja00076j

ZHANG Y ， ZHANG T L ， LI H . Application of laser-induced breakdown spectroscopy （LIBS） in environmental monitoring ［J］. Spectrochimica Acta Part B： Atomic Spectroscopy ， 2021 ， 181 ： 106218 . doi: 10.1016/j.sab.2021.106218 http://dx.doi.org/10.1016/j.sab.2021.106218

MELIKECHI N ， MEZZACAPPA A ， COUSIN A ， et al . Correcting for variable laser-target distances of laser-induced breakdown spectroscopy measurements with ChemCam using emission lines of Martian dust spectra ［J］. Spectrochimica Acta Part B： Atomic Spectroscopy ， 2014 ， 96 ： 51 - 60 . doi: 10.1016/j.sab.2014.04.004 http://dx.doi.org/10.1016/j.sab.2014.04.004

VANIMAN D ， DYAR M D ， WIENS R ， et al . Ceramic ChemCam calibration targets on Mars science laboratory ［J］. Space Science Reviews ， 2012 ， 170 （ 1 ）： 229 - 255 . doi: 10.1007/s11214-012-9886-0 http://dx.doi.org/10.1007/s11214-012-9886-0

MANARD B T ， JR C D Q ， BRADLEY V C ， et al . Uranium single particle analysis for simultaneous fluorine and uranium isotopic determinations via laser-induced breakdown spectroscopy/laser ablation-multicollector-inductively coupled plasma-mass spectrometry ［J］. Journal of the American Chemical Society ， 2024 ， 146 （ 21 ）： 14856 - 14863 . doi: 10.1021/jacs.4c03965 http://dx.doi.org/10.1021/jacs.4c03965

MA L X ， YANG X N ， XUE S S ， et al . "Raman plus X" dual-modal spectroscopy technology for food analysis： a review ［J］. Comprehensive Reviews in Food Science and Food Safety ， 2025 ， 24 （ 1 ）： e70102 . doi: 10.1111/1541-4337.70102 http://dx.doi.org/10.1111/1541-4337.70102

DONG Y T ， JI H C ， WU X X ， et al . Trends of sustainable recycling technology for lithium-ion batteries： Metal recovery from conventional metallurgical processes to innovative direct recycling ［J］. MetalMat ， 2024 ， 1 （ 1 ）： e5 . doi: 10.1002/metm.5 http://dx.doi.org/10.1002/metm.5

SAFI A ， LANDIS J E ， ADLER H G ， et al . Enhancing biomarker detection sensitivity through tag-laser induced breakdown spectroscopy with NELIBS ［J］. Talanta ， 2024 ， 271 ： 125723 . doi: 10.1016/j.talanta.2024.125723 http://dx.doi.org/10.1016/j.talanta.2024.125723

KHUMAENI A ， BUDI W S ， HEDWIG R ， et al . Spectrochemical analysis of stainless steel using 355nm and 1064nm Nd： YAG laser-induced breakdown spectroscopy ［J］. Arabian Journal for Science and Engineering ， 2024 ， 49 （ 7 ）： 10193 - 10200 . doi: 10.1007/s13369-024-09015-4 http://dx.doi.org/10.1007/s13369-024-09015-4

LI H C ， LIU T Y ， FU Y C ， et al . Improving the accuracy of high-repetition-rate LIBS based on laser ablation and scanning parameters optimization ［J］. Optics Express ， 2022 ， 30 （ 21 ）： 37470 - 37483 . doi: 10.1364/oe.470782 http://dx.doi.org/10.1364/oe.470782

GRAVEL J Y ， DOUCET F R ， BOUCHARD P ， et al . Evaluation of a compact high power pulsed fiber laser source for laser-induced breakdown spectroscopy ［J］. Journal of Analytical Atomic Spectrometry ， 2011 ， 26 （ 7 ）： 1354 - 1361 . doi: 10.1039/c0ja00228c http://dx.doi.org/10.1039/c0ja00228c

GUO L B ， CHENG X ， TANG Y ， et al . Improvement of spectral intensity and resolution with fiber laser for on-stream slurry analysis in laser-induced breakdown spectroscopy ［J］ . Spectrochimica Acta Part B： Atomic Spectroscopy ， 2019 ， 152 ： 38 - 43 . doi: 10.1016/j.sab.2018.12.007 http://dx.doi.org/10.1016/j.sab.2018.12.007

LV C ， ZHANG N ， LIN Z J ， et al . Determination of copper， magnesium， and manganese in aluminum alloys using laser-induced breakdown spectroscopy based on fiber laser ablation ［J］. Journal of Laser Applications ， 2023 ， 35 （ 1 ）： 012021 . doi: 10.2351/7.0000939 http://dx.doi.org/10.2351/7.0000939

LI T Q ， HOU Z Y ， FU Y T ， et al . Correction of self-absorption effect in calibration-free laser-induced breakdown spectroscopy （CF-LIBS） with blackbody radiation reference ［J］. Analytica Chimica Acta ， 2019 ， 1058 ： 39 - 47 . doi: 10.1016/j.aca.2019.01.016 http://dx.doi.org/10.1016/j.aca.2019.01.016

XU Z Y ， XU B H ， PENG X Y ， et al . Laser-ablation dependence of fiber-laser-based laser-induced breakdown spectroscopy for determining Cu， Mg， and Mn elements in aluminum alloys ［J］. Journal of Analytical Atomic Spectrometry ， 2021 ， 36 （ 11 ）： 2501 - 2508 . doi: 10.1039/d1ja00188d http://dx.doi.org/10.1039/d1ja00188d

CIUCCI A ， CORSI M ， PALLESCHI V ， et al . New procedure for quantitative elemental analysis by laser-induced plasma spectroscopy ［J］. Applied Spectroscopy ， 1999 ， 53 （ 8 ）： 960 - 964 . doi: 10.1366/0003702991947612 http://dx.doi.org/10.1366/0003702991947612

SUN L X ， YU H B . Correction of self-absorption effect in calibration-free laser-induced breakdown spectroscopy by an internal reference method ［J］. Talanta ， 2009 ， 79 （ 2 ）： 388 - 395 . doi: 10.1016/j.talanta.2009.03.066 http://dx.doi.org/10.1016/j.talanta.2009.03.066

QIN Y Z ， XU Z Y ， CAI D S ， et al . Experimental investigation of the self-absorption effect in laser-induced breakdown spectroscopy based on fiber laser ablation ［J］. Spectroscopy ， 2025 ， 40（wp7）. doi: 10.56530/spectroscopy.rd2690f6 http://dx.doi.org/10.56530/spectroscopy.rd2690f6

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Stimulated Brillouin scattering self Q-switching generates high-power white light supercontinuum spectrum

Study on LIBS system for high-precision coal components rapid and quantitative analysis

Wavelength-switchable cylindrical vector fiber laser based on symmetrical two-mode coupler

Picosecond pulsed near infrared supercontinuum laser

Yb-doped fiber MOPA system with radially polarized output beam based on LCP vortex retarder

Related Author

GE Tingwu

JIA Ruoyu

LI Guanzheng

ZHAO Guanrui

ZHANG Wenqi

LI Qingxuan

XUE Chuang

LIU Shulin

Related Institution

School of Noncommissioned Officers， Army Academy of Armored Forces

School of Physics and Optoelectronic Engineering， Beijing University of Technology

School of Physics， Beijing Institute of Technology

School of Mechanical Engineering， Xi’an University of Science and Technology， Xian

Science and Technology on Solid-state Laser Laboratory， No.11th Research Institute of China Electronics Technology Group Corporation

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176855 Email：gxjmgc@ciomp.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰