On-line detection of carbon dioxide in large scale offshore by laser technology

Ming-xing LI; Bing CHEN; Jun RUAN; Xiang LI; Ying LIU; Zhen-yu XU; Ya-bai HE; Rui-feng KAN

doi:10.37188/OPE.20202807.1424

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On-line detection of carbon dioxide in large scale offshore by laser technology

Modern Applied Optics | 更新时间：2020-08-13

- On-line detection of carbon dioxide in large scale offshore by laser technology
- Optics and Precision Engineering Vol. 28, Issue 7, Pages: 1424-1432(2020)
- 作者机构：
  
  1.中国科学院合肥物质科学研究院安徽光学精密机械研究所, 安徽合肥 230031
  2.中国科学技术大学, 安徽合肥 230026
  3.中国科学院长春光学精密机械与物理研究所, 吉林长春 130033
- 作者简介：
- 基金信息：
- DOI：10.37188/OPE.20202807.1424
  CLC： O433.1;O657.38
- Received：16 December 2019，
  
  Revised：24 December 2019，
  
  Accepted：24 December 2019，
  
  Published：15 July 2020
- 稿件说明：
移动端阅览
Ming-xing LI, Bing CHEN, Jun RUAN, et al. On-line detection of carbon dioxide in large scale offshore by laser technology[J]. Optics and precision engineering, 2020, 28(7): 1424-1432.
DOI：

Ming-xing LI, Bing CHEN, Jun RUAN, et al. On-line detection of carbon dioxide in large scale offshore by laser technology[J]. Optics and precision engineering, 2020, 28(7): 1424-1432. DOI： 10.37188/OPE.20202807.1424.

摘要

陆地或海洋与大气之间的能量和物质交换的定量研究，特别是二氧化碳（CO

）交换通量的监测，对研究全球碳循环以及气候变化具有重要意义。基于直接吸收光谱技术和导数吸收光谱技术，采用收发一体式光学系统，研制了开放式CO

在线探测样机，测量区域可达到km量级。利用Allan方差分析了系统检测限，当积分时间达到100 s时，检测限为0.08×10

-6

。使用不同浓度的标准气体，验证了二阶导数光谱用于浓度反演方法的可行性，得到相关性为0.998。样机在深圳市生态环境监测站连续运行1个月，探测结果具有明显的日变化周期性。与安装于附近不同点位的Licor7550-CO

监测仪进行数据对比，数据变化趋势吻合，且样机稳定性更优。

Abstract

Quantitative research on energy and material exchange between the land or ocean and the atmosphere

especially the monitoring of carbon dioxide (CO

) exchange flux

play an important role in the study of global carbon cycle and climate change.We developed an open-path CO

detection system based on direct absorption spectroscopy technology and derivative spectroscopy technology for on-line measurement across an order of km air path. A movable platform was developed capable of detecting atmospheric variations of CO

in real time with the integrated optical system of transceiver.Allan variance analysis shows the detection limit of the system is 0.08×10

-6

at the integration time of 100 s.The feasibility of the method with the second derivative spectrum is verified by using standard gases with different concentrations for the concentration calibration

and the correlation is 0.998. The continuous operation was carried out at Shenzhen Eco-environment Monitoring Station for 1 month

and the detection results have obvious daily variation periodicity.Comparing the data with the Licor7550-CO

monitor installed at different points nearby

the data change trend is consistent

and the stabilityof the prototype is better.

关键词

Keywords

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