Fast optical cavity ring-down spectroscopy detection based on first harmonic frequency locking

HU Mai; CHEN Xiang; ZHANG Hui; HU Mengpeng; JIN Wenling; LI Meng; KAN Ruifeng

doi:10.37188/OPE.20223004.0363

您当前的位置：

首页 >

文章列表页 >

Fast optical cavity ring-down spectroscopy detection based on first harmonic frequency locking

Modern Applied Optics | 更新时间：2026-09-12

- Fast optical cavity ring-down spectroscopy detection based on first harmonic frequency locking
- Optics and Precision Engineering Vol. 30, Issue 4, Pages: 363-371(2022)
- 作者机构：
  
  1.中国科学院合肥物质科学研究院安徽光学精密机械研究所，安徽合肥230031
  2.中国科学技术大学，安徽合肥 230026
  3.中国科学院长春光学精密机械与物理研究所，吉林长春 130033
  4.哈尔滨工业大学可调谐激光技术国家级重点实验室，黑龙江哈尔滨 150001
- 作者简介：
- 基金信息：
- DOI：10.37188/OPE.20223004.0363
  CLC： TP391;TH691.9
- Received：27 August 2021，
  
  Revised：2021-10-11，
  
  Published：25 February 2022
- 稿件说明：
移动端阅览
胡迈,陈祥,张辉等.一次谐波锁频的快速光腔衰荡光谱检测[J].光学精密工程,2022,30(04):363-371.

HU Mai,CHEN Xiang,ZHANG Hui,et al.Fast optical cavity ring-down spectroscopy detection based on first harmonic frequency locking[J].Optics and Precision Engineering,2022,30(04):363-371.
胡迈,陈祥,张辉等.一次谐波锁频的快速光腔衰荡光谱检测[J].光学精密工程,2022,30(04):363-371. DOI： 10.37188/OPE.20223004.0363.

HU Mai,CHEN Xiang,ZHANG Hui,et al.Fast optical cavity ring-down spectroscopy detection based on first harmonic frequency locking[J].Optics and Precision Engineering,2022,30(04):363-371. DOI： 10.37188/OPE.20223004.0363.

摘要

本文介绍了一种赫兹级响应速率的光腔衰荡光谱探测大气痕量气体的检测技术。将100 MHz正弦波调制信号加载在电光相位调制器上产生边带，用混频器提取载波与边带通过3 m气体吸收池后拍频所产生的一次谐波作为误差信号，实现了1 572 nm分布式反馈激光器对于二氧化碳气体分子6 361.25 cm

处超精细跃迁线的频率锁定。采用波分复用方法对空腔衰荡时间和有气体吸收时的衰荡时间进行同时测量，在330 mm光学谐振腔上得到了4.82×10

的系统检测限。在较大的二氧化碳浓度范围内，系统具有良好的线性响应，线性相关系数大于0.999 9。系统长时间的观测结果与Picarro商用仪器的数据高度吻合，二者偏差小于1.0%。该系统论证了一次谐波锁定激光频率至分子超精细跃迁线并用于光腔衰荡光谱系统实现快速痕量气体检测的可行性。

Abstract

Optical cavity ring-down spectroscopy with a Hz-level response rate is introduced to detect trace gases in the atmosphere. By loading a 100 MHz modulated sine wave signal on the electro-optic phase modulator that generates sidebands and using the mixer to extract the first harmonic generated as the error signal by the beat frequency of the carrier and sidebands after passing through the 3 m gas absorption cell， the frequency locking of a 1 572 nm distributed feedback laser on the 6 361.25 cm

hyperfine transition line of carbon dioxide gas molecule was achieved. The ring-down time of the cavity without gas and the ring-down time with gas absorption were simultaneously measured using the wavelength-division multiplexing method， and the detection limit of the system obtained was 4.82×10

on a 330 mm optical resonator. The system has a good linear response in a large carbon dioxide concentration range， and the linear correlation coefficient is greater than 0.999. The long-term observation results of the system are highly consistent with the data from Picarro commercial instruments， and the deviation between the two is less than 1.0%. The system

proved the feasibility of locking the laser frequency to the molecular hyperfine transition line using the first harmonic and applying it to the optical cavity ring-down spectroscopy system to achieve a fast trace gas detection.

关键词

Keywords

references

MAITY A ， MAITHANI S ， PRADHAN M . Cavity ring-down spectroscopy： recent technological advancements， techniques， and applications ［J］. Analytical Chemistry ， 2021 ， 93 （ 1 ）： 388 - 416 . doi: 10.1021/acs.analchem.0c04329 http://dx.doi.org/10.1021/acs.analchem.0c04329

杜星湖，薛颖，何星，等 . 基于耦合光腔衰荡技术的高反射率测量［J］. 中国激光， 2020 ， 47 （ 6 ）： 0604006 . doi: 10.3788/CJL202047.0604006 http://dx.doi.org/10.3788/CJL202047.0604006

DU X H ， XUE Y ， HE X ， et al . High reflectivity measurement based on coupled cavity ring-down technique ［J］. Chinese Journal of Lasers ， 2020 ， 47 （ 6 ）： 0604006 . （in Chinese） . doi: 10.3788/CJL202047.0604006 http://dx.doi.org/10.3788/CJL202047.0604006

THIÉBAUD J ， FITTSCHEN C . Near infrared cw-CRDS coupled to laser photolysis： Spectroscopy and kinetics of the HO 2 radical ［J］. Applied Physics B ， 2006 ， 85 （ 2/3 ）： 383 - 389 . doi: 10.1007/s00340-006-2304-0 http://dx.doi.org/10.1007/s00340-006-2304-0

CHEN Y ， LEHMANN K K ， KESSLER J ， et al . Measurement of the 13 C/ 12 C of atmospheric CH 4 using near-infrared （NIR） cavity ring-down spectroscopy ［J］. Analytical Chemistry ， 2013 ， 85 （ 23 ）： 11250 - 11257 . doi: 10.1021/ac401605s http://dx.doi.org/10.1021/ac401605s

MORVILLE J ， KASSI S ， CHENEVIER M ， et al . Fast， low-noise， mode-by-mode， cavity-enhanced absorption spectroscopy by diode-laser self-locking ［J］. Applied Physics B ， 2005 ， 80 （ 8 ）： 1027 - 1038 . doi: 10.1007/s00340-005-1828-z http://dx.doi.org/10.1007/s00340-005-1828-z

TRUONG G W ， DOUGLASS K O ， MAXWELL S E ， et al . Frequency-agile， rapid scanning spectroscopy ［J］. Nature Photonics ， 2013 ， 7 （ 7 ）： 532 - 534 . doi: 10.1038/nphoton.2013.98 http://dx.doi.org/10.1038/nphoton.2013.98

HUA T P ， SUN Y R ， WANG J ， et al . Frequency metrology of molecules in the near-infrared by NICE-OHMS ［J］. Optics Express ， 2019 ， 27 （ 5 ）： 6106 - 6115 . doi: 10.1364/oe.27.006106 http://dx.doi.org/10.1364/oe.27.006106

BLACK E D . An introduction to Pound–Drever–Hall laser frequency stabilization ［J］. American Journal of Physics ， 2001 ， 69 （ 1 ）： 79 - 87 . doi: 10.1119/1.1286663 http://dx.doi.org/10.1119/1.1286663

李明星，陈兵，阮俊，等 . 近海大尺度区域二氧化碳的激光在线探测技术［J］. 光学精密工程， 2020 ， 28 （ 7 ）： 1424 - 1432 . doi: 10.37188/OPE.20202807.1424 http://dx.doi.org/10.37188/OPE.20202807.1424

LI M X ， CHEN B ， RUAN J ， et al . On-line detection of carbon dioxide in large scale offshore by laser technology ［J］. Opt. Precision Eng. ， 2020 ， 28 （ 7 ）： 1424 - 1432 . （in Chinese） . doi: 10.37188/OPE.20202807.1424 http://dx.doi.org/10.37188/OPE.20202807.1424

聂伟，许振宇，阚瑞峰，等 . 可调谐二极管激光吸收光谱技术测量低温流场水汽露点温度［J］. 光学精密工程， 2018 ， 26 （ 8 ）： 1862 - 1869 . doi: 10.3788/OPE.20182608.1862 http://dx.doi.org/10.3788/OPE.20182608.1862

NIE W ， XU Z Y ， KAN R F ， et al . Measurement of low water vapor dew-point temperature based on tunable diode laser absorption spectroscopy ［J］. Opt. Precision Eng. ， 2018 ， 26 （ 8 ）： 1862 - 1869 . （in Chinese） . doi: 10.3788/OPE.20182608.1862 http://dx.doi.org/10.3788/OPE.20182608.1862

袁峰，高晶，姚路，等 . 球载CRDS高灵敏度甲烷测量系统的研制［J］. 光学精密工程， 2020 ， 28 （ 9 ）： 1881 - 1892 . doi: 10.37188/OPE.20202809.1881 http://dx.doi.org/10.37188/OPE.20202809.1881

YUAN F ， GAO J ， YAO L ， et al . Development of highly sensitive balloon-borne methane measurement system based on cavity ringdown spectroscopy ［J］. Opt. Precision Eng. ， 2020 ， 28 （ 9 ）： 1881 - 1892 . （in Chinese） . doi: 10.37188/OPE.20202809.1881 http://dx.doi.org/10.37188/OPE.20202809.1881

DUDEK J B ， TARSA P B ， VELASQUEZ A ， et al . Trace moisture detection using continuous-wave cavity ring-down spectroscopy ［J］. Analytical Chemistry ， 2003 ， 75 （ 17 ）： 4599 - 4605 . doi: 10.1021/ac0343073 http://dx.doi.org/10.1021/ac0343073

HE Y B ， ORR B J . Ringdown and cavity-enhanced absorption spectroscopy using a continuous-wave tunable diode laser and a rapidly swept optical cavity ［J］. Chemical Physics Letters ， 2000 ， 319 （ 1/2 ）： 131 - 137 . doi: 10.1016/s0009-2614(00)00107-x http://dx.doi.org/10.1016/s0009-2614(00)00107-x

GIUSFREDI G ， BARTALINI S ， BORRI S ， et al . Saturated-absorption cavity ring-down spectroscopy ［J］. Physical Review Letters ， 2010 ， 104 （ 11 ）： 110801 . doi: 10.1103/physrevlett.104.110801 http://dx.doi.org/10.1103/physrevlett.104.110801

李想 . 海水关键溶解气体高灵敏激光原位分析方法研究［D］. 合肥：中国科学技术大学， 2020 .

LI X . Dissolved Gases Measurements in Seawater Using High Sensitivity Laser Spectrometer Technology ［D］. Hefei ： University of Science and Technology of China ， 2020 . （in Chinese）

NICKERSON M . A review of Pound-Drever-Hall laser frequency locking ［J］. JILA， University of Colorado and NIST ， 2019 .

BAHOURA M ， CLAIRON A . Ultimate linewidth reduction of a semiconductor laser frequency-stabilized to a Fabry-Perot interferometer ［J］. IEEE Transactions on Ultrasonics， Ferroelectrics， and Frequency Control ， 2003 ， 50 （ 11 ）： 1414 - 1421 . doi: 10.1109/tuffc.2003.1251124 http://dx.doi.org/10.1109/tuffc.2003.1251124

SU J ， JIAO M X ， JIANG F . Pound-Drever-Hall laser frequency locking technique based on orthogonal demodulation ［J］. Optik ， 2018 ， 168 ： 348 - 354 . doi: 10.1016/j.ijleo.2018.04.098 http://dx.doi.org/10.1016/j.ijleo.2018.04.098

ROTHMAN L S ， JACQUEMART D ， BARBE A ， et al . The HITRAN 2004 molecular spectroscopic database ［J］. Journal of Quantitative Spectroscopy and Radiative Transfer ， 2005 ， 96 （ 2 ）： 139 - 204 . doi: 10.1016/j.jqsrt.2004.10.008 http://dx.doi.org/10.1016/j.jqsrt.2004.10.008

SIMECKOVA M ， JACQUEMART D ， ROTHMAN L S ， et al . Einstein A-coefficients and statistical weights for molecular absorption transitions in the HITRAN database ［J］. Journal of Quantitative Spectroscopy and Radiative Transfer ， 2006 ， 98 （ 1 ）： 130 - 55 . doi: 10.1016/j.jqsrt.2005.07.003 http://dx.doi.org/10.1016/j.jqsrt.2005.07.003

Views

2465

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

OPE | Fast optical cavity ring-down spectroscopy detection based on first harmonic frequency locking

Interference lithography of space-variant grating structures by phase modulation

Fiber interferometer based on phase generated carrier method

Optimization and validation of the differential interferometric surface plasmon resonance sensor

Research of the phase-only modulation characterization of a liquid crystal spatial light modulator

Inverse design of efficient achromatic metalens based on channel attention enhanced network

Related Author

YE Yan

CHEN Linsen

XU Yishen

XU Fengchuan

LU Chang

Ming ZHANG

Yu ZHU

Chang NI

Related Institution

School of Optoelectronic Science and Engineering， Soochow University

Suzhou City University

Collaborative Innovation Center of Suzhou Nano Science and Technology， Soochow University

Key Lab of Advanced Optical Manufacturing Technologies of Jiangsu Province & Key Lab of Modern Optical Technologies of Education Ministry of China， Soochow University

State Key Laboratory of Tribology, Department of Mechanical Engineering, Tsinghua University

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176855 Email：gxjmgc@ciomp.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰