Application of cavity-enhanced gas Raman spectroscopy in gas logging

Andong KONG; Dewang YANG; Jinjia GUO; Lulu WU; Aoshuang YAN; Faju ZHOU; Yaqi WAN

doi:10.37188/OPE.20223010.1151

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Application of cavity-enhanced gas Raman spectroscopy in gas logging

Modern Applied Optics | 更新时间：2022-06-21

- Application of cavity-enhanced gas Raman spectroscopy in gas logging
- Optics and Precision Engineering Vol. 30, Issue 10, Pages: 1151-1159(2022)
- 作者机构：
  
  1.中国海洋大学物理与光电工程学院，山东青岛 266100
  2.山东科技大学海洋科学与工程学院，山东青岛 266590
  3.中石化胜利石油工程有限公司地质录井公司，山东东营 257000
- 作者简介：
- 基金信息：
- DOI：10.37188/OPE.20223010.1151
  CLC： O433.4
- Received：19 November 2021，
  
  Revised：04 January 2022，
  
  Published：25 May 2022
- 稿件说明：
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孔安栋,杨德旺,郭金家等.腔增强气体拉曼光谱仪在气测录井中的应用[J].光学精密工程,2022,30(10):1151-1159.

KONG Andong,YANG Dewang,GUO Jinjia,et al.Application of cavity-enhanced gas Raman spectroscopy in gas logging[J].Optics and Precision Engineering,2022,30(10):1151-1159.
孔安栋,杨德旺,郭金家等.腔增强气体拉曼光谱仪在气测录井中的应用[J].光学精密工程,2022,30(10):1151-1159. DOI： 10.37188/OPE.20223010.1151.

KONG Andong,YANG Dewang,GUO Jinjia,et al.Application of cavity-enhanced gas Raman spectroscopy in gas logging[J].Optics and Precision Engineering,2022,30(10):1151-1159. DOI： 10.37188/OPE.20223010.1151.

摘要

目前气测录井主要采用气相色谱分析，气相色谱需要氢气助燃，氢气和持续的火焰有一定危险性需要远离井口，从而导致气体探测时间延迟，拉曼光谱有望解决这一问题。针对气测录井现场高灵敏度、快速多组分气体检测的需求，研发了一套基于腔增强的气体拉曼光谱检测系统，该系统灵敏度高、体积小、安全方便、可实现烷烃、氢气和二氧化碳等多种气体同时探测。本文首先描述了系统的设计与参数，然后在实验室测试了该系统对于烷烃气体和非烃气体进行分析的工作性能，实验结果表明该气体拉曼光谱检测系统对甲烷、氢气和二氧化碳的探测线性度良好，检测限分别为30 ppm、201 ppm和495 ppm。之后将该系统于山东东营胜利油田进行了现场试验，并与气测录井的气相色谱仪分析结果进行对比，实验结果表明，拉曼光谱系统与气相色谱仪分析结果吻合度较高，相比气相色谱具有更高的时间分辨率，同时能够探测到气相色谱所不能探测的氢气等气体浓度变化趋势，满足气测录井现场高灵敏度、快速及多组分检测的需求。

Abstract

Currently， gas logging relies primarily on the use of a gas chromatograph equipped with a flame ionization detector， whose sustaining flame must be distanced from the wellhead for safety. However， the elongated sampling tube delays the response time of detection. To meet the requirements of high sensitivity and rapid multi-component gas detection in gas logging， a gas Raman spectroscopy detection system based on multi-reflection cavity enhancement is developed. This system is compact and portable and can detect numerous gases， including alkanes， hydrogen， and carbon dioxide， simultaneously with high sensitivity. In this study， we first describe the design and parameters of the gas Raman spectroscopy detection system， followed by testing the working performance of the Raman system for analyzing alkane gases and non-hydrocarbon gases. Experimental results demonstrate that the gas Raman spectroscopy detection system has good linearity for methane， hydrogen， and carbon dioxide detection. The limits of detection were 30， 201， and 495 ppm， respectively. Finally， the system was applied to the Shengli oilfield in Dongying， Shandong province， China. The experimental results of the Raman spectroscopy system are in good agreement with those from the gas chromatograph method. Unlike gas chromatographic devices， the developed Raman system has the capability of detecting hydrogen and offering advantages in time resolution. In conclusion， the Raman system design used in this study can fulfill the requirements of high sensitivity and rapid and multi-component detection in gas logging.

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references

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