. Controllable factors in detection of pulverized coal flow with LIBS[J]. Editorial Office of Optics and Precision Engineering, 2013,21(7): 1651-1658 DOI: 10.3788/OPE.20132107.1651.
Controllable factors in detection of pulverized coal flow with LIBS
It is necessary to optimize operable factors in measurement of pulverized coal flow by Laserinduced Breakdown Spectroscopy(LIBS). Therefore
this paper investigated the effects of three main operable factors, irradiance
integration delay time and the rate of flow per unit area on the measurement of pulverized coal flow by LIBS based on orthogonal experiments. Pulverized coal was chosen for the experimental sample and the statistic analysis and variance analysis were performed. Experiment indicates that the irradiance and integration delay time are two remarkable factors for the effective excitation rate and the following is the rate of flow per unit area. The optimum parameters of control from the experiment are the irradiance of 9.41011 W/cm2
the integration delay time of 1 500 ns, and the rate of flow is selected reasonably based on economy principles. The results obtained demonstrate that the method can direct the practical measurement of pulverized coal flows in real time.
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仇韬,丁艳军,孔亮,等.CFB 锅炉动态特性与负荷和煤质的关系研究[J].中国电机工程学报,2007,27(32):46-51.QIU T,DING Y J,KONG L,et al..Research of relationship between CFBB dynamic behavior and power and coal quality[J].Proceedings of the CSEE,2007,27(32):46-51.(in Chinese)[2]CREMERS D A,RADZIEMSKI L J.Handbook of Laser-induced Breakdown Spectroscopy[M].West Sussex:John Wiley & Sons Ltd.[3]HUANG J S,KE C B,HUANG L S,et al..The correlation between ion production and emission intensity in the laser-induced breakdown spectroscopy of liquid droplets[J].Spectrochimica Acta Part B,2002, 57 (1) :35-48.[4]MAO X L,SHANNON M A,FERNANDEZ A J,et al..Temperature and emission spatial profiles of laser-induced plasmas during ablation using time-integrated emission spectroscopy [J].Applied Spectroscopy,1995,49(7):1054-1062.[5]SARKAR A,SHAH R V,ALAMELU D,et al..Studies on the ns-IR-laser-induced plasma parameters in the vanadium oxide[J].Journal of Atomic, Molecular, and Optical Physics,2011,17:504-704.[6]BODY D, CHADWICK B L.Simultaneous elemental analysis system using laser induced breakdown spectroscopy [J].Review of Scientific Instruments,2011,72(3):1625-1629.[7]GAFT M,SAPIR-SOFER I,MODIANO H,et al..Laser induced breakdown spectroscopy for bulk minerals online analyses[J].Spectrochimica Acta Part B-Atomic Spectroscopy,2007,62(12):1496-1503.[8]MATEO M P,NICOLAS G,YANEZ A.Characterization of inorganic species in coal by laser-induced breakdown spectroscopy using UV and IR radiations[J].Applied Surface Science,2007,254(4):868-872 .[9]NODA M,DEGUCHI Y,IWASAKI S,et al..Detection of carbon content in a high-temperature and high-pressure environment using laser-induced breakdown spectroscopy[J].Spectrochimica Acta Part B-Atomic Spectroscopy,2002,57(4):701-709.[10]KURIHARA M, IKEDA K, IZAWA Y,et al..Optimal boiler control through real-time monitoring of unburned carbon in fly ash by laser-induced breakdown spectroscopy[J].Applied Optics,2003,42(30):6159-6165.[11]TOGNONI E,PALLESCHI V,CORSI M.Quantitative micro-analysis by laser-induced breakdown spectroscopy:a review of the experimental approach [J].Spectrochimica Acta Part B,2002,57 (7):1115-1130.[12]李捷,陆继东,谢承利,等.激光感生击穿煤质实验中延迟时间的研究[J].光谱学与光谱分析,2008,28(4):736-739.LI J,LU J D, XIE CH L,et al..Investigation on the delay time of coal experiment by laser-induced breakdown spectroscopy[J].Spectroscopy and Spectral Analysis,2008,28(4):736-739.(in Chinese)[13]谢承利,陆继东,李捷,等.激光诱导煤粉发射光谱的基体效应研究[J].工程热物理学报,2008,29(2):331-334.XIE CH L,LU J D,LI J,et al..Matrix effect on laser-induced breakdown spectroscopy of fine coal[J].Journal of Engineering Thermophysics,2008,29(2) :331-334.(in Chinese)[14]BODY D,CHADWICK B L.Optimization of the spectral data processing in a LIBS simultaneous elemental analysis system [J].Spectrochimica Acta Part B:Atomic Spectroscopy,2001,56(6):725-736.[15]HONG M H,LU Y F,BONG S K.Time-resolved plasma emission spectrum analyses at the early stage of laser ablation[J].Applied Surface Science,2000,154:196-200.[16]TAMBAY R,THAREJA R K.Laser-induced breakdown studies of laboratory air at 0.266, 0.355, 0.532, and 1.06 m [J].Journal of Applied Physics,1991,70(5):2890-2892.[17]章玉珠,王广安,沈中华,等.等离子体屏蔽和稀疏波对冲量耦合系数的影响[J].强激光与粒子束,2007,19 (4):585-585.ZHANG Y ZH,WANG G A,SHEN ZH H,et al..Influences of plasma shielding and rarefaction wave on impulse coupling coefficient[J].High Power Laser and Particle Beams,2007,19 (4):585-585.(in Chinese)[18]姚顺春,陆继东,谢承利,等.激光能量对粉煤灰未燃碳测量的影响[J].光谱学与光谱分析,2009,29(8):2025-2029.YAO SH CH,LU J D,XIE CH L, et al..Impact of laser energy on measurement of fly ash carbon content[J].Spectroscopy and Spectral Analysis.2009,29(8):2025-2029.(in Chinese)[19]CORSI M,CRISTOFORETTI G,HIDALGO M,et al..Temporal and spatial evolution of a laser-induced plasma from a steel target[J].Applied Spectroscopy,2003,57(6):715-721.[20]ROMERO D,ROMERO J M F,LASERNA J J,et al..Distribution of metal impurities in silicon wafers using imaging-mode multi-elemental laser-induced breakdown spectrometry [J].Journal of Analytical Atomic Spectrometry,1999,14(2):199-204.