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1. 中国科学院 研究生院,北京 100039
2. 中国科学院 长春光学精密机械与物理研究所,吉林 长春,130031
3. 长春职业技术学院,吉林 长春,130031
收稿日期:2007-04-13,
修回日期:2007-06-29,
网络出版日期:2007-10-30,
纸质出版日期:2007-10-30
移动端阅览
沈永宏,闫冬梅,王琦. 多孔体坩埚生长氟化钙晶体[J]. 光学精密工程, 2007,15(10):1474-1477
SHEN Yong-hong, YAN Dong-mei, WANG Qi. Calcium fluoride crystal growth with multi-hole-crucible[J]. Optics and precision engineering, 2007, 15(10): 1474-1477.
采用独特设计的多孔体坩埚和自行设计的晶体生长炉
在真空条件下
用Bridgman-Stockbarger法生长出了CaF
2
光学晶体。在真空度低于3×10
-3
Pa
生长区中心轴温度梯度为1.8~2.5 ℃/mm
径向梯度<0.5 ℃/mm
生长速率为3~4 mm/h
初退火降温速率控制在20 ℃/h以下的生长条件下
进行熔料、氟化去氧、均一化熔体、控速生长及初退火
一炉次生长了七根57 mm×190 mm的CaF
2
光学晶体
并进行了性能分析。结果表明
生长出的晶体透带宽
从紫外190 nm到红外9 000 nm均有良好的透过率
190 nm处透过率可达81%
9 000 nm处透过率可达83%
单晶率可达80%
位错密度达30/mm
2
。使用本文提出的设备和工艺
提高了CaF
2
晶体的单晶率
降低了使用损耗
可实现中小尺寸CaF
2
晶体的规模化生产。
By using a multi-hole-crucible and a furnace designed by ourselves
the CaF
2
crystals were grown by Bridgman-Stockbarger method under the vacuum condition. Under the growing condition of the vacuum below 3×10
-3
Pa
the axial gradient in growing zone about 1.8~2.5 ℃/mm
radial gradient below 0.5 ℃/mm
growing velocity of 3~4 mm/h and pre-annealing temperature descending velocity below 20 ℃/h
7 ingots of CaF
2
crystals with size of Φ57 mm×190 mm were grown in single process by melting
scavenging
homogenizing
controlling velocity and pre-annealing. The results show that the grown crystals with a wide transparent band have a good performance from 190 nm in ultra-violet to 9 000 nm in infra-red. The transmissivity is about 81% at 190 nm and 83% at 9 000 nm. The rate of mono-crystal is about 80%. The dislocation is about 30/mm
2
. The proposed equipment and technology are suited to batch production of CaF
2
crystals.
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