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浙江工业大学 机械制造及自动化教育部重点实验室,浙江 杭州,310032
收稿日期:2008-08-05,
修回日期:2008-09-27,
网络出版日期:2009-07-25,
纸质出版日期:2009-07-25
移动端阅览
许雪峰, 马冰迅, 黄亦申, 彭伟. 利用复合磨粒抛光液的硅片化学机械抛光[J]. 光学精密工程, 2009,17(7): 1587-1593
XU Xue-feng, MA Bing-xun, HUANG Yi-shen, PENG Wei. Chemical mechanical polishing for silicon wafer by composite abrasive slurry[J]. Editorial Office of Optics and Precision Engineering, 2009,17(7): 1587-1593
为了提高硅片的抛光速率
利用复合磨粒抛光液对硅片进行化学机械抛光。分析了SiO
2
磨粒与聚苯乙烯粒子在溶液中的
电位及粒子间的相互作用机制
观察到SiO
2
磨粒吸附在聚苯乙烯及某种氨基树脂粒子表面的现象。通过向单一磨粒抛光液中加入聚合物粒子的方法获得了复合磨粒抛光液。对硅片传统化学机械抛光与利用复合磨粒抛光液的化学机械抛光进行了抛光性能研究
提出了利用复合磨粒抛光液的化学机械抛光技术的材料去除机理
并分析了抛光工艺参数对抛光速率的影响。 实验结果显示
利用单一SiO
2
磨料抛光液对硅片进行抛光的抛光速率为180 nm/min;利用SiO
2
磨料与聚苯乙烯粒子或某氨基树脂粒子形成的复合磨粒抛光液对硅片进行抛光的抛光速率分别为273 nm/min和324 nm/min。结果表明
利用复合磨粒抛光液对硅片进行抛光提高了抛光速率
并可获得
R
a
为
0.2 nm
的光滑表面。
In order to increase the polishing rate for a silicon wafer
the composite abrasive slurry was used in Chemical Mechanical Polishing(CMP). Zeta potentials of silica abrasives and polystyrene particles in the slurry were measured at various pH values
and the mechanism of interactions between silica abrasives and polymer particles was analyzed. Small silica abrasives were observed to attach onto the surfaces of the polystyrene particles and some resin particles.Then
the composite abrasive slurry was obtained by adding some polymer particles into single abrasive slurry. In comparison with the polishing performance of traditional CMP and CMP using composite abrasive slurry
the mechanism of material removal of CMP using composite abrasive slurry was proposed
and the influence of craft parameters on the polishing rate was studied through the experiments. Experimental results indicate that the polishing rate is 180 nm/min with single silica abrasive slurry
and 273 nm/min
324 nm/min with the silica abrasive/polystyrene particle composite slurry and silica abrasive/ resin particle composite slurry respectively. These data show that the removal rate with composite abrasive slurry is improved significantly and the wafer surface roughness
R
a
is 0.2 nm.
吕玉山,王军,张辽远,等. 护环对硅片抛光表面压强分布和轮廓的影响[J]. 光学 精密工程,2008,16(4):689-695. LU Y SH,WANG J,ZHANG L Y, et al.. Effect of retaining on pressure distribution and profile of polishing wafer surface [J]. Opt. Precision Eng. , 2008,16(4):689-695. (in Chinese)[2] 曹志强,赵继,陈德祥,等. 硅晶片的液流悬浮超光滑加工机理与实验[J]. 光学 精密工程,2007,15(7):1084-1089. CHAO ZH Q, ZHAO J, CHENG D X, et al.. Theory and experiment on hydrodynamic suspensionultra2smooth machining for silicon wafers [J]. Opt. Precision Eng., 2007,15(7):1084-1089. (in Chinese)[3] 张厥宗.硅单晶抛光片的加工技术[M]. 北京:化学工业出版社,2005. ZHANG J Z. Machining Technology of Monocrystalline Silicon Wafer[M]. Beijing: Chemical Industry Press, 2005. (in Chinese)[4] YANO H, MATSUI Y, MINAMIHABA G, et al.. High-performance CMP slurry with inorganic/resin abrasive for Al/low k damascene[J]. Mat. Res. Soc. Symp. Proc. 2001, 671: M2.4.1-M2.4.6.[5] ARMINI S, WHELAN C M, MAEXB K, et al.. Composite polymer-core silica-shell abrasive particles during oxide CMP: a defectivity study [J]. Journal of the Electrochemical Society, 2007,154(8):H667-H671. [6] 杨志甫,杨辉,李成贵,等. 基于HHT的微晶玻璃超光滑表面抛光[J]. 光学 精密工程,2008,16(1):35-41. YANG ZH F, YANG H, LI CH G, et al..Supersmooth polishing of zerodur based on HHT [J]. Opt. Precision Eng . , 2008,16(1):35-41. (in Chinese)[7] ARMINI S, WHELAN C M, MOINPOUR M,et al.. Composite polymer core-silica shell abrasives effect of polishing time and slurry solid content on oxide CMP[J]. Electrochemical and Solid-State Letters, 2007,10(9):H243-H247.[8] 刑颖. 纳米二氧化硅水悬浮液的稳定性研究[J]. 涂料工业, 2006, 36(8):58-60. XING Y. Study on stability of nano-SiO2 aqueous suspension [J]. Paint & Coatings Industry,2006, 36(8): 58-60. (in Chinese)
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