非线性光学聚合物电光活性稳定性的快速老化模型实验

王希军; 苏少昌

doi:10.3788/OPE.20111902.0387

您当前的位置：

首页 >

文章列表页 >

非线性光学聚合物电光活性稳定性的快速老化模型实验

现代应用光学 | 更新时间：2020-08-12

- 非线性光学聚合物电光活性稳定性的快速老化模型实验
- Fast aging experiment of EO chromophore stability of dopant polyquinoline polymers
- 光学精密工程 2011年19卷第2期页码：387-391
- 作者机构：
  
  1. 中国科学院长春光学精密机械与物理研究所,吉林长春,中国,130033
  2. 中国科学院研究生院北京,100049
- 作者简介：
- 基金信息：
  
  应用光学国家重点实验室应用光学基金资助项目(No.DA04Q05)()
- DOI：10.3788/OPE.20111902.0387
  中图分类号： O437;O484.1
- 收稿日期：2010-10-08，
  
  修回日期：2010-10-30，
  
  网络出版日期：2011-02-22，
  
  纸质出版日期：2011-02-22
- 稿件说明：
移动端阅览
王希军, 苏少昌. 非线性光学聚合物电光活性稳定性的快速老化模型实验[J]. 光学精密工程, 2011,19(2): 387-391

WANG Xi-jun, SU Shao-chang. Fast aging experiment of EO chromophore stability of dopant polyquinoline polymers[J]. Editorial Office of Optics and Precision Engineering, 2011,19(2): 387-391
王希军, 苏少昌. 非线性光学聚合物电光活性稳定性的快速老化模型实验[J]. 光学精密工程, 2011,19(2): 387-391 DOI： 10.3788/OPE.20111902.0387.

WANG Xi-jun, SU Shao-chang. Fast aging experiment of EO chromophore stability of dopant polyquinoline polymers[J]. Editorial Office of Optics and Precision Engineering, 2011,19(2): 387-391 DOI： 10.3788/OPE.20111902.0387.

摘要

利用旋涂法制取了掺杂型非线性光学聚喹啉材料的高分子材料薄膜

并用平板电场极化法对NLO聚喹啉材料的高分子材料薄膜进行了极化。然后

利用锁相放大器测量并给出了该高分子材料的线性电光系数(

)衰减曲线

唯象地引入双指数衰减模型的常数项

并据此模型得到了新的拟合曲线。提出了永久线性电光系数

()系数和稳定性比

的参数描述及其物理依据。完成了1 300 nm和1 550 nm波长快速老化模型测量实验

分析了实验观察到的电光(EO)系数随时间衰减的现象及变化规律。利用此实验直接测量极化聚合物薄膜的电光系数

对于二阶聚合物的筛选和波导器件的制作具有指导意义。

Abstract

Polymer films from dopant Nolinear Optics(NLO) polymers were prepared by the spinning and coating method

then the films were poled by the electric field polarization.The EO coefficient

attenuation curves of poled NLO chromophore doped in polyquinoline were measured by a lock-in amplifier technology. Relying on the EO

experiment curves and theoretical biexponential function models

the constant items defined as the permanent EO coefficient

and defined as stability ratio

idealistically were introduced

so that the characteristic properties of EO NLO polymer were described. In addition

the attenuations of EO coefficient

with relaxation in 1 300 nm and 1 550 nm wavelength were discussed to observe the changes in the characterization experiments.Obtained results show that the EO coefficient

is the important parameters to describe the characteristic properties of these materials

and it can directly measure the EO coefficient

of the poled NLO polymers in selecting the NLO materials and manufacturing the wave-guide devices.

关键词

Keywords

references

TERPSTRA T, FIDDER H, WIERSMA D A. A nonlinear optical study of Frenkel excitions in Langmuir-Blodgett [J]. Chem. Phys. Lett., 1991,179:349-354.[2] 刘成有,宁丹,ZHANG B P, 等. ZnO薄膜非线性特性的实验研究 [J]. 光学精密工程,2005,13(3):265-271. LIU CH Y, NING D, ZHANG B P, et al.. Nonlinear optical properties of ZnO films deposited by metalorganic chemical vapor deposition (MOCVD) technique [J]. Opt. Precision Eng., 2005,13(3):265-271. (in Chinese)[3] 徐松,吴秋萍,李忠玉. 方酸衍生物的三阶非线性光学特性 [J]. 光学精密工程,2007, 15(11):1674-1678. XU S, WU Q P, LI ZH Y. Third-order optical nonliearities of squaraine derivatives [J]. Opt. Precision Eng., 2007,15(11):1674-1678 . (in Chinese)[4] CHEN H, CHEN B, DINU R, et al.. Broadband electro-optic polymer modulators with high electro-optic activity and low poling induced optical loss [J]. Appl. Phys. Lett., 2008, 93:043507.[5] ENAMI Y, MATHINE D,PEYGHAMBARIAN N, et al.. Hybrid electro-optic polymer/sol-gel waveguide directional coupler switches [J]. Appl. Phys. Lett., 2009,94:213513.[6] DALTON L R, SULLIVAN P A, BALE D H, et al.. Electric field poled organic electro-optic materials: state of the art and future prospects [J]. Chem. Rev., 2010,110(1):25-55.[7] SU H, TAE-DONG K, ALEX K Y J, et al.. Highly efficient electro-optic polymers through improved poling using a thin TiO2-modified transparent electrode [J]. Appl. Phys. Lett., 2010,96, 243311.[8] TENG C C,MAN H T. Simple reflection technique for measuring the electro-optic coefficient of poled polymers [J]. Appl. Phys. Lett., 1990,56(18):1734-1736.[9] NORWOOD R A,KUZYK M G, KEOSIAN R A, et al.. Electro-optic tensor ratio determination of side-chain copolymers with electro-optic interferometry [J]. J. Appl. Phys., 1994,75:1869.[10] KHANARIAN G,ALLEN D, STAMATOFF J B, et al.. Electro-optic characterization of nonlinear-optical guest-host films and polymers [J]. J.Opt. Soc. Am. B,1996,13:1927.[11] GREENLEE C,GUIMO A, PEYGHAMBARIAN N, et al.. Mach-Zehnder interferometry method for decoupling electro-optic and piezoelectric effects in poled polymer films [J]. J. Appl. Phys., 2010,97:041109.[12] STILLE J K. Polyquinolines [J]. Macromolecules, 1981,14:870.[13] AGRAUAL A K,JENEKHE S A. Synthesis and processing of heterocyclic polymers as electronic, optoelectronic, and nonlinear optical materials. 2. new series of conjugated rigid-rod polyquinolines and polyanthrazolines [J]. Macromolecules, 1993,26:895.[14] HUBBARD M A,MARKS T J,YANG J, et al.. poled polymeric nonlinear opitical materials. enhanced second harmonic generation stability of croo-linkable matrix/chromophore ensembles [J]. Chem.. Mater., 1989, 1(2):167.[15] CAI Y M,JEN A K Y. Thermally stable poled polyquinoline thin film with very large electro-optic response [J]. Appl. Phys. Lett., 1995, 67(3):299.

浏览量

430

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

暂无数据