用动态光散射时间相干度法测量纳米颗粒粒径

杨晖; 郑刚; 张仁杰

doi:10.3788/OPE.20111907.1546

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用动态光散射时间相干度法测量纳米颗粒粒径

现代应用光学 | 更新时间：2020-08-12

- 用动态光散射时间相干度法测量纳米颗粒粒径
- Measurement of nanoparticle sizes by variance of temporal coherence of dynamic light scattering
- 光学精密工程 2011年19卷第7期页码：1546-1551
- 作者机构：
  
  上海理工大学光电信息与计算机工程学院上海,200093
- 作者简介：
- 基金信息：
  
  国家自然科学基金资助项目(No.61007002)();上海市晨光计划资助项目(No.10CG50)();上海市重点学科资助项目(No.J50505, S30502)(
- DOI：10.3788/OPE.20111907.1546
  中图分类号： TB92;TH741.4
- 收稿日期：2010-09-13，
  
  修回日期：2010-11-18，
  
  网络出版日期：2011-07-25，
  
  纸质出版日期：2011-07-25
- 稿件说明：
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杨晖, 郑刚, 张仁杰. 用动态光散射时间相干度法测量纳米颗粒粒径[J]. 光学精密工程, 2011,19(7): 1546-1551

YANG Hui, ZHENG Gang, ZHANG Ren-jie. Measurement of nanoparticle sizes by variance of temporal coherence of dynamic light scattering[J]. Editorial Office of Optics and Precision Engineering, 2011,19(7): 1546-1551
杨晖, 郑刚, 张仁杰. 用动态光散射时间相干度法测量纳米颗粒粒径[J]. 光学精密工程, 2011,19(7): 1546-1551 DOI： 10.3788/OPE.20111907.1546.

YANG Hui, ZHENG Gang, ZHANG Ren-jie. Measurement of nanoparticle sizes by variance of temporal coherence of dynamic light scattering[J]. Editorial Office of Optics and Precision Engineering, 2011,19(7): 1546-1551 DOI： 10.3788/OPE.20111907.1546.

摘要

针对传统动态光散射法测量纳米颗粒粒径算法复杂、速度慢、成本高等问题

提出了一种通过改变动态散射光信号时间相干度来测量纳米颗粒粒径的方法

并对其所采用的算法和测量系统进行研究。首先

介绍了动态光散射测量法的基本原理

并引出系统相干度的概念(包括时间相干因子和空间相干因子)。接着

从光电探测器的统计特性出发

通过对光子计数方差的分析得到散射光强波动的方差。然后

建立光强波动的方差与时间相干度的方程

并由该方程得到动态光散射信号的衰减线宽。最后

根据Stokes-Einstein公式计算出纳米颗粒的粒径。对粒径为30

100 nm

溶液透光率为96%的乳胶球标准颗粒溶液进行了实验

结果表明:本文提出的测量法其测量均值误差和重复性误差的平均值分别为1.84%和1.76%

满足均值误差和重复性误差小于2%的国标要求。

Abstract

A measurement method of nanoparticle sizes by the variance of temporal coherence of dynamic light scattering was presented to resolve problems of complex algorithms

slow operation

and high costs of traditional dynamic light scattering nano-particle measurement systems and its algorithm and measurement system were studied

respectively. Firstly

the photon correlation spectroscopic theory of dynamic light scattering measurement was introduced

and the concept of coherence degree which includes a temporal coherence factor and a spatial coherence factor was deduced. Then

based on the statistical properties of photoelectric detectors

the variance of the fluctuation of scattering intensity was deduced through analysis of the variance of photon counting. The equations of the variance of intensity fluctuations and the temporal coherence degree were established

and the decay width of a dynamic light scattering signal was obtained by the equations. Finally

the particle diameters of the nano-particles were calculated by the Stokes-Einstein equation.Furthermore

the latex particle sample solution with the diameters of 30

100 nm and the transmission of 96% was used as the standard sample to be tested in an experiment. The results show that the average values of the measurement error and repeatability error of the new method are 1.84% and 1.76%

respectively

which satisfies the national standard that these errors should be less than 2%

respectively.

关键词

Keywords

references

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