Eu3+掺杂硼酸银玻璃制备、表征及其在白光发光二极管中的应用

赵文倩; 张映辉; 付少博; 陈宝玖

doi:10.3788/OPE.20152313.0172

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Eu³⁺掺杂硼酸银玻璃制备、表征及其在白光发光二极管中的应用

更新时间：2020-08-13

- Eu³⁺掺杂硼酸银玻璃制备、表征及其在白光发光二极管中的应用
- Preparation and characterization of Eu³⁺ doped silver borate glasses and their applications in white light emitting diodes
- 光学精密工程 2015年23卷第10z期页码：173-178
- 作者机构：
  
  大连海事大学物理系,辽宁大连,116026
- 作者简介：
- 基金信息：
  
  国家自然科学基金资助项目(No.11374044,No.11104023,No.11104024,No.11274057)();中央高校基本科研业务费专项基金资助项目(
- DOI：10.3788/OPE.20152313.0172
  中图分类号： O482.3;TQ171.71
- 收稿日期：2015-06-19，
  
  修回日期：2015-07-03，
  
  纸质出版日期：2015-11-14
- 稿件说明：
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赵文倩, 张映辉, 付少博等. Eu3+掺杂硼酸银玻璃制备、表征及其在白光发光二极管中的应用[J]. 光学精密工程, 2015,23(10z): 173-178

ZHAO Wen-qian, ZHANG Ying-hui, FU Shao-bo etc. Preparation and characterization of Eu3+ doped silver borate glasses and their applications in white light emitting diodes[J]. Editorial Office of Optics and Precision Engineering, 2015,23(10z): 173-178
赵文倩, 张映辉, 付少博等. Eu3+掺杂硼酸银玻璃制备、表征及其在白光发光二极管中的应用[J]. 光学精密工程, 2015,23(10z): 173-178 DOI： 10.3788/OPE.20152313.0172.

ZHAO Wen-qian, ZHANG Ying-hui, FU Shao-bo etc. Preparation and characterization of Eu3+ doped silver borate glasses and their applications in white light emitting diodes[J]. Editorial Office of Optics and Precision Engineering, 2015,23(10z): 173-178 DOI： 10.3788/OPE.20152313.0172.

摘要

研究了采用玻璃荧光体实现白光发光二极管(LED)的可能性。采用熔融淬火技术制备了一系列Eu

掺杂的含不同比例银成分的硼酸银玻璃

并对玻璃的结构、光谱及色度学性质进行了研究。X射线衍射测量证明在其能分辨的水平上样品中没有银粒子存在

而吸收光谱测量观察到了高含量银成分的样品中含有银纳米颗粒;样品的激发和发射光谱测量表明近紫外光可有效激发样品并产生覆盖几乎全部可见波段的发射;荧光衰减测量表明样品中含有多种Ag聚集体发光中心。计算了样品的发射色坐标

结果显示一定组分的Eu

掺杂硼酸银可实现色坐标为(0.312

0.336)

显色指数为88的白光发射。最后

利用390 nm发射半导体二极管和30 mol % AgNO

的玻璃样品成功制作了白光发射器件。

Abstract

The feasibility to produce white light emitting diodes by using glass phosphors was explored

and a series of Eu

doped silver borate glasses with various silver contents were prepared via a melt-quenching technique. The structural

spectral and chromatic properties of the glasses were studied. X-ray diffraction (XRD) patterns indicate that there are no silver particles in glasses in the identifiable level that the XRD could reach

but absorption spectra exhibit the existence of silver nanoparticles in the glasses with higher silver contents. Furthermore

the excitation and emission spectra show that the glass samples can be effectively excited by near ultraviolet and can generate emissions covering almost full visible region. Fluorescence decays demonstrate that there are many types of silver aggregates in the glass samples. The color coordinate was calculated

and it shows that white light generation can be obtained from Eu

doped silver borate glass samples with certain composition. Finally

a white emitting device was produced by using the glass with the color coordinate of (0.312

0.336) and a color rending index of 0.88 and a 390 nm diode.

关键词

Keywords

references

LIU Y F, ZHANG X, HAO Z D, et al.. A new dual-emission phosphor Ca4Si2O7F2:Ce3+, Mn2+ with energy transfer for near-UV LEDs [J]. Materials Letters, 2012, 77(15): 45-47.

邵文尧,何彩云,胡超群,等. LED发光材料的制备及应用前景[J]. 化工技术与开发,2014,43(6): 51-55. SHAO W R, HE C Y, HU CH Q, et al.. Preparation and application prospect of LED light-emitting materials[J]. Technology & Decelopment of Chemical Industry,2014,43(6): 51-55. (in Chinese)

SETLUR A A. Phosphors for LED-based solid-state lighting[J]. Electrochemical Society Interface, 2009,18: 32-36.

LE TOQUIN R, CHEETHAM A K. Red-emitting cerium-based phosphor materials for solid-state lighting applications[J]. Chemical Physics Letters, 2006,423(4-6): 352-356.

殷录桥,翁菲,宋朋,等. LED芯片与YAG荧光粉的相互热作用[J]. 光学学报, 2014,34(4):1-7. YIN L Q, WENG F, SONG P, et al.. Thermal interact effects of LED chip with YAG phosphor layer[J]. Acta Optica Sinica, 2014,34(4): 1-7.(in Chinese)

PARK J Y, LEE J H, RAJU G S R, et al.. Synthesis and luminescent characteristics of yellow emitting GdSr2AlO5: Ce 3+ phosphor for blue light based white LED[J]. Ceramics International, 2014,40(4): 5693-5698.

SETLUR A A,SHIANG J J,HANNAH M E,et al.. Phosphor quenching in LED packages: measurements, and paths forward[J]. SPIE, 2009,7422,74220E: 1-8.

乔君. 钪硅酸盐白光LED荧光粉的研究 [D].长春: 中国科学院长春光学精密机械与物理研究所, 2014. QIAO J. Studies on Scandium Silicate Phosphors for White LEDs[D]. Changchun: University of Chinese Academy of Sciences, 2014. (in Chinese)

LI X F, DUDAI J D, LIU F,et al.. New yellow Ba0.93Eu0.07Al2O4 phosphor for warm-white light-emitting diodes through single-emitting-center conversion[J]. Light Science & Applications, 2013,2(1): 1-8.

陆晓军. 稀土掺杂长余辉发光玻璃的研究 [D].长春: 中国科学院长春光学精密机械与物理研究所, 2006. LU X J.Study of Rare Earth Ions Doped Long Luminescence Glass[D]. Changchun: Changchun Institute of Optics and Fine Mechanics and Physics, Chinese Academy of Sciences, 2006. (in Chinese)

梁晓峦. 白光LED用稀土离子/过渡金属离子掺杂发光玻璃的制备及性能研究 [D].上海:华东理工大学,2010. LIANG X L.Study on the Preparation of Rare Earth Ions/Transition Metal Ions Doped Luminescence Glass for W-LED Applications[D]. Shanghai:East China University of Science and Technology, 2010. (in Chinese)

ZHU D M, LOU X, LUO F,et al.. Preparation and properties of borate glass coatings on Ti-based alloy substrate[J]. Transactions of Nonferrous Metals Society of China, 2007,S1: 766-769.

BROW R K, SAHA S K, GOLDSTEIN J I. Interfacial reactions between titanium and borate glass[C].Materials Research Society Symposium Proceedings, 1993, 314: 77-81.

李晓坤,张友林,孔祥贵. Ag纳米粒子聚集体的SiO2包覆及其SERS效应[J]. 发光学报, 2014,35(7): 853-857. LI X K, ZHANG Y L, KONG X G. Aggregation of Ag nanoparticles coated with silica and its SERS effect[J]. Chinese Journal of Luminescence, 2014,35(7): 853-857. (in Chinese)

杨艳民, 陈宝玖, 王成. 玻璃中银粒子对稀土离子发光影响的研究[J]. 中国稀土学报, 2008,26(2): 213-216. YANG Y M, CHEN B J, WANG CH. Effect of silver particles on spectroscopic properties of rare earth in glasses[J]. Journal of the Chinese Rare Earth Society, 2008,26(2): 213-216.(in Chinese)

刘惠玉,陈东,高继宁,等. 贵金属纳米材料的液相合成及其表面等离子体共振性质应用[J]. 化学进展,2006,18(7/8): 889-896. LIU H Y, CHEN D, GAO J N, et al..Liquid phase fabrication of noble metal nanomaterials and their surface plasmon resonance-based applications[J]. Progress in Chemistry, 2006,18(7/8): 889-896. (in Chinese)

张金苏 . 晶体中稀土离子f-f跃迁光谱强度的研究 [D]. 长春:中国科学院长春光学精密机械与物理研究所, 2010. ZHANG J S.Spectral Intensities of f-f Transitions in Rare-Earth Ions Doped Crystals [D]. Changchun: Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, 2010. (in Chinese)

LI P L, XU Z, ZHAO S L, et al.. Enhancement of green emission by the codoping A+ (A=Li,Na,K) in Ca2BO3Cl : Tb3+ phosphor[L]. Chinese Physics B, 2013,22(8):0878031-4.

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