用于调味品中非法添加物测定的便携式激光拉曼检测仪

张溱; 杨练根; 张娜; 何涛; 翟中生

doi:10.3788/OPE.20162413.0203

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用于调味品中非法添加物测定的便携式激光拉曼检测仪

更新时间：2020-08-13

- 用于调味品中非法添加物测定的便携式激光拉曼检测仪
- A portable laser Raman detector used for detecting illegal additives in condiment
- 光学精密工程 2016年24卷第10s期页码：203-211
- 作者机构：
  
  1. 湖北工业大学机械工程学院,湖北武汉,430068
  2. 湖北省现代制造质量工程重点实验室,湖北武汉,430068
- 作者简介：
- 基金信息：
  
  湖北省科技支撑计划资助项目（No.2015BCE047）()
- DOI：10.3788/OPE.20162413.0203
  中图分类号： TH742
- 收稿日期：2016-06-05，
  
  修回日期：2016-07-05，
  
  纸质出版日期：2016-11-14
- 稿件说明：
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张溱, 杨练根, 张娜等. 用于调味品中非法添加物测定的便携式激光拉曼检测仪[J]. 光学精密工程, 2016,24(10s): 203-211

ZHANG Zhen, Yang Lian-gen, ZHANG Na etc. A portable laser Raman detector used for detecting illegal additives in condiment[J]. Editorial Office of Optics and Precision Engineering, 2016,24(10s): 203-211
张溱, 杨练根, 张娜等. 用于调味品中非法添加物测定的便携式激光拉曼检测仪[J]. 光学精密工程, 2016,24(10s): 203-211 DOI： 10.3788/OPE.20162413.0203.

ZHANG Zhen, Yang Lian-gen, ZHANG Na etc. A portable laser Raman detector used for detecting illegal additives in condiment[J]. Editorial Office of Optics and Precision Engineering, 2016,24(10s): 203-211 DOI： 10.3788/OPE.20162413.0203.

摘要

为了实现调味品中的非法添加物的现场快速检测，提出了一种基于激光拉曼原理的便携式拉曼检测仪。它主要由785 nm波长的激光器、分光镜、聚焦透镜、滤光镜、光谱仪、光谱分析软件以及便携式计算机等组成。基于拉曼原理设计了拉曼聚焦光路和收集光路，并设计了基于免疫遗传算法和粒子群算法对拉曼光谱重叠峰进行精确解析的光谱分析软件。通过实验，配合银离子拉曼增强剂和匹配剂，对1×10

-6

的罗丹明B和碱性橙Ⅱ的混合水溶液进行了光谱采集，获取了相应的拉曼光谱信号，然后对这2种存在重叠峰的非法添加物进行了检测。结果表明本仪器能有效分离拉曼光谱的重叠峰，其理论测量分辨率为2.3×10

-9

，包括简单制备和仪器预热在内的检测时间小于半小时，可辅助食品质量监督部门进行现场执法检验和取证。

Abstract

Aiming at on-line fast detection of illegal additives

a portable Raman detector

consisting of 785 nm wavelength laser

spectroscope

focusing lens

glass filter

spectrometer

spectral analysis software and portable computer etc.

was developed based on laser Raman principle. The focus light path and gathering light path were designed. Then the spectral analysis software was designed for accurate analysis on overlapping peaks of Raman spectrum by using the immune genetic algorithm and the particle swarm optimization algorithm. Subjected to silver ion Raman fortifier and matching agent

the mixed solution of 1×10

-6

Rhodamine B and Basic Orange II was detected by the portable Raman detector experimentally. From the Raman spectrum signals

the illegal additives with overlapping peaks were identified. The instrument can effectively separate overlapping peaks of Raman spectrum with the measurement resolution ratio of 2.3×10

-9

and detection time including simple preparation and preheating of instrument lower than half an hour

which can provide assistance for food quality supervision departments.

关键词

Keywords

references

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