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1.中国航天科工飞航技术研究院 天津津航技术物理研究所 天津市薄膜光学重点实验室, 天津 300308
2.哈尔滨工业大学 光电子技术研究所 可调谐激光技术国防科技重点实验室, 黑龙江 哈尔滨 150001
刘华松(1980-),男,辽宁阜新人,博士,研究员,主要从事高性能与特种光学薄膜的设计、制备与表征、固体光学薄膜材料等方面的研究。E-mail:liuhuasong@hotmail.com E-mail:liuhuasong@hotmail.com
收稿日期:2016-08-30,
录用日期:2016-9-14,
纸质出版日期:2017-01-25
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刘华松, 杨霄, 王利栓, 等. 离子束溅射氧化钽薄膜的光学带隙特性[J]. 光学精密工程, 2017,25(1):21-27.
Hua-song LIU, Xiao YANG, Li-shuan WANG, et al. Characteristics of optical band gap of tantalum oxide thin film deposited by ion beam sputtering[J]. Editorial office of optics and precision engineeri, 2017, 25(1): 21-27.
刘华松, 杨霄, 王利栓, 等. 离子束溅射氧化钽薄膜的光学带隙特性[J]. 光学精密工程, 2017,25(1):21-27. DOI: 10.3788/OPE.20172501.0021.
Hua-song LIU, Xiao YANG, Li-shuan WANG, et al. Characteristics of optical band gap of tantalum oxide thin film deposited by ion beam sputtering[J]. Editorial office of optics and precision engineeri, 2017, 25(1): 21-27. DOI: 10.3788/OPE.20172501.0021.
Ta
2
O
5
薄膜是可见光到近红外波段中重要的高折射率薄膜材料之一。本文针对离子束溅射制备Ta
2
O
5
薄膜的光学带隙特性开展了实验研究工作,基于Cody-Lorentz模型表征了薄膜的光学带隙特性,重点针对薄膜的禁带宽度和Urbach带尾宽度与制备参数之间的相关性进行研究。研究结果表明:在置信概率95%以上时,对Ta
2
O
5
薄膜禁带宽度影响的制备参数,权重大小依次为氧气流量、基板温度、离子束电压;而对Ta
2
O
5
薄膜Urbach带尾宽度影响的制备参数,权重大小依次为基板温度和氧气流量。对于Ta
2
O
5
薄膜在超低损耗激光薄膜和高损伤阈值激光薄膜领域内应用,本文的研究结果给出了同步提高薄膜的禁带宽度和降低带尾宽度的重要工艺参数选择方法。
The Ta
2
O
5
thin film is one of the most important high refractive materials in the range from visible to near infrared. This paper researched the optical band gap of the Ta
2
O
5
thin film which was deposited by the Ion Beam Sputtering (IBS). The optical band gap was characterized by the Cody-Lorentz dispersion model. Particularly
the correlations of the band gap and the Urbach with technological parameters were studied respectively. The results show that when the confidence probability is over 95%
the technological parameters are ranked due to their influence coefficients on the band gap as follows: oxygen flow
substrate temperature
and ion beam voltage. Accordingly due to those on the Urbach
the technological parameters are ranked as substrate temperature and oxygen flow. The result provides a method for choosing the key technological parameters to increase the band gap width and reduce the Urbach energy width simultaneously of the Ta
2
O
5
thin film used in the areas of the ultra-low loss thin film and high laser-induced damage threshold thin film.
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刘华松, 季一勤, 张锋, 等. 金属氧化物薄膜在中波红外光谱区内光学常数色散特性[J]. 光学学报, 2014, 34(8):0831003.
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