小型高灵敏度水下拉曼光谱系统

刘庆省; 郭金家; 杨德旺; 司赶上; 郑荣儿

doi:10.3788/OPE.20182601.0008

您当前的位置：

首页 >

文章列表页 >

小型高灵敏度水下拉曼光谱系统

现代应用光学 | 更新时间：2020-08-13

- 小型高灵敏度水下拉曼光谱系统
- A compact underwater Raman spectroscopy system with high sensitivity
- 光学精密工程 2018年26卷第1期页码：8-13
- 作者机构：
  
  中国海洋大学光学光电子实验室, 山东青岛 266100
- 作者简介：
  
  [ "刘庆省(1991-), 男, 山东聊城人, 2015年于山东科技大学获得学士学位, 主要从事激光探测方面的研究。E-mail:qingxing_liu@foxmail.com" ]
  [ "郭金家(1979-), 男, 高级工程师, 2001年于山东师范大学获得学士学位, 2004年、2012年于中国海洋大学分别获得硕士和博士学位, 主要从事海洋激光探测技术的研究。E-mail:opticsc@ouc.edu.cn" ]
- 基金信息：
  
  国家重点研发计划资助项目(2016YFC0302101);国家自然科学基金资助项目(61575181)
- DOI：10.3788/OPE.20182601.0008
  中图分类号： TH744.1;O433.1
- 收稿日期：2017-05-27，
  
  录用日期：2017-7-10，
  
  纸质出版日期：2018-01-25
- 稿件说明：
移动端阅览
刘庆省, 郭金家, 杨德旺, 等. 小型高灵敏度水下拉曼光谱系统[J]. 光学精密工程, 2018,26(1):8-13.

Qing-xing LIU, Jin-jia GUO, De-wang YANG, et al. A compact underwater Raman spectroscopy system with high sensitivity[J]. Optics and precision engineering, 2018, 26(1): 8-13.
刘庆省, 郭金家, 杨德旺, 等. 小型高灵敏度水下拉曼光谱系统[J]. 光学精密工程, 2018,26(1):8-13. DOI： 10.3788/OPE.20182601.0008.

Qing-xing LIU, Jin-jia GUO, De-wang YANG, et al. A compact underwater Raman spectroscopy system with high sensitivity[J]. Optics and precision engineering, 2018, 26(1): 8-13. DOI： 10.3788/OPE.20182601.0008.

摘要

为了使水下拉曼光谱系统更加易于搭载和布放，并进一步提高其探测能力，研制了一套探头式的小型高灵敏度水下拉曼光谱系统并对其探测能力进行了评估。通过优化结构设计和严格的器件选型，系统的体积和重量得到了有效的控制，其主体舱尺寸为

260 mm×L795 mm，重量为548 N，仅为国际上报道的首台深海拉曼光谱系统（DORISS）质量的三分之一。将激光器从主体舱移至探头舱，有效避免了传统光学探头中激发光耦合进入光纤时产生的耦合损失以及激光在传输过程中引起的杂散光干扰。系统采用了300 mW能量可调激光器配合高衍射效率的体相位全息光栅和半导体制冷CCD，有效提高了探测灵敏度。实验结果表明，系统对于硫酸根的检测限在0.4 mmol·L

-1

以下，是DORISS探测能力的4倍，同时能够实现对水下矿石种类的原位鉴定。该深海拉曼光谱系统在海洋原位探测方面展现出了良好的应用前景。

Abstract

In order to reduce the volume and weight of the underwater Raman system

and to improve its portability and detection sensitivity

a compact underwater Raman spectroscopy system with high sensitivity was developed and assessed. Through elaborate selection of components

a compact structural design was realized with both the weight and the volume well controlled. The size of the main body was kept at 795 mm in length and 260 mm in diameter

with a weight of 548 N

one third of the weight of reported DORISS (the first deep ocean Raman

in-situ

spectroscopy system). The laser was housed in the optical probe rather than in the main body

hence higher excitation efficiency was achieved with high power density. There are two advantages to put the laser head in the probe. A desirable excitation power density could be obtained without the consumption of laser beam during transmission in fiber

and better signal to noise ratio could be achieved without the stray light raised by the interaction of laser and optical fiber. In addition

300 mW powered laser

efficient volume phase holographic grating and TEC cooled CCD detector were used to improve the system performance. The experimental results show that the LOD (limit of detection) of SO

was less than 0.4 mmol·L

-1

. It's about four times than the value achieved by DORISS. Meanwhile the system can be used to identify minerals. All above prove the system to be highly potential in ocean exploration.

关键词

Keywords

references

刘燕德, 谢庆华, 王海阳, 等.山茶油和橄榄油品质和掺假定量分析的对比研究[J].光学精密工程, 2016, 24(10):600-606.

LIU Y D, XIE Q H, WANG H Y, et al .. Comparative study on camellia oil & olive oil quality and quantitative analysis of adulteration[J]. Opt. Precision Eng ., 2016, 24(10):600-606. (in Chinese)

刘燕德, 靳昙昙, 王海阳.基于拉曼光谱的三组分食用调和油快速定量检测[J].光学精密工程, 2015, 23(9):2490-2496.

LIU Y D, JIN T T, WANG H Y. Rapid quantitative determination of components in ternary blended edible oil based on Raman spectroscopy[J]. Opt. Precision Eng ., 2015, 23(9):2490-2496. (in Chinese)

吴斌, 骆晓森, 陆建, 等.用激光拉曼频移测定乙醇水溶液的浓度[J].光学精密工程, 2011, 19(2):392-396.

WU B, LUO X S, LU J, et al .. Determination of ethanol concentration of aqueous solution by using Raman stretching frequency shifts[J]. Opt. Precision Eng ., 2011, 19(2):392-396. (in Chinese)

BREWER P G, MALBY G, PASTERIS J D, et al .. Development of a laser Raman spectrometer for deep-ocean science[J]. Deep Sea Research Part Ⅰ: Oceanographic Research Papers , 2004, 51(5):739-753.

HESTER K C, DUNK R M, WHITE S N, et al .. Gas hydrate measurements at Hydrate Ridge using Raman spectroscopy[J]. Geochimica et Cosmochimica Acta , 2007, 71(12):2947-2959.

HESTER K C, WHITE S N, PELTZER E T, et al .. Raman spectroscopic measurements of synthetic gas hydrates in the ocean[J]. Marine Chemistry , 2006, 98(2-4):304-314.

WHITE S N, DUNK R M, PELTZER E T, et al .. In situ Raman analyses of deep-sea hydrothermal and cold seep systems (Gorda Ridge and Hydrate Ridge)[J]. Geochemistry, Geophysics, Geosystems , 2006, 7(5):Q05023.

ZHANG X, DU Z F, ZHENG R E, et al . . In situ Raman-based detections of the hydrothermal vent and cold seep fluids[C]. EGU General Assembly Conference Abstracts, EGU, 2016, 18: 3428. http://adsabs.harvard.edu/abs/2016EGUGA..18.3428Z

BREIER J A, WHITE S N, GERMAN C R. Mineral-microbe interactions in deep-sea hydrothermal systems:a challenge for Raman spectroscopy[J]. Philosophical Transactions of the Royal Society of London A : Mathematical, Physical and Engineering Sciences , 2010, 368(1922):3067-3086.

WHITE S N, KIRKWOOD W, SHERMAN A, et al .. Development and deployment of a precision underwater positioning system for in situ laser Raman spectroscopy in the deep ocean[J]. Deep Sea Research Part Ⅰ:Oceanographic Research Papers , 2005, 52(12):2376-2389.

SHERMAN A D, WALZ P M, BREWER P G. Two generations of deep-ocean Raman in situ spectrometers[J]. Sea Technology , 2007, 48(2):10-13.

ZHANG X, KIRKWOOD W J, WALZ P M, et al .. A review of advances in deep-ocean Raman spectroscopy[J]. Applied Spectroscopy , 2012, 66(3):237-249.

程凯, 侯华明, 李德平, 等.深海原位激光拉曼光谱系统释样设计与海试[J].哈尔滨工程大学学报, 2011, 32(8):1058-1062.

CHENG K, HOU H M, LI D P, et al .. Design and sea trial on a sample releasing device used for deep-sea in-situ laser Raman spectroscopy system[J]. Journal of Harbin Engineering University , 2011, 32(8):1058-1062. (in Chinese)

PASTERIS J D, WOPENKA B, FREEMAN J J, et al .. Raman spectroscopy in the deep ocean:successes and challenges[J]. Applied Spectroscopy , 2004, 58(7):195A-208A.

杜增丰. 基于DOCARS和LCOF-Raman的酸根离子探测和沉积物孔隙水的光谱分析[D]. 青岛: 中国海洋大学, 2015. http://www.wanfangdata.com.cn/details/detail.do?_type=degree&id=Y2884828

DU Z F. Detection of Acid Radical Ions with DOCARS and LCOF-Raman System and Spectral Analysis of Sediment Pore Water [D]. Qingdao: Ocean University of China, 2015. (in Chinese)

DU Z F, LI Y, CHEN J, et al .. Feasibility investigation on deep ocean compact autonomous Raman spectrometer developed for in-situ detection of acid radical ions[J]. Chinese Journal of Oceanology and Limnology , 2015, 33(2):545-550.

WALRAFEN G E, HOKMABADI M S, YANG W H. Raman isosbestic points from liquid water[J]. The Journal of Chemical Physics , 1986, 85(12):6964-6969.

TERPSTRA P, COMBES D, ZWICK A. Effect of salts on dynamics of water:a Raman spectroscopy study[J]. The Journal of Chemical Physics , 1990, 92(1):65-70.

BREIER J A, GERMAN C R, WHITE S N. Mineral phase analysis of deep-sea hydrothermal particulates by a Raman spectroscopy expert algorithm:toward autonomous in situ experimentation and exploration[J]. Geochemistry, Geophysics, Geosystems , 2009, 10(5):Q05T05.

浏览量

343

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

高灵敏度、高精度的光栅应变传感系统

面向CMB偏振实验的220 GHz钛超导TES探测器技术研究

基于层状PI薄膜FBG传感器的KCl浓度测量

腔增强气体拉曼光谱仪在气测录井中的应用

透射式光学系统焦平面鬼像特性及验证