激光熔覆原位自生Ti-Al-Si复合涂层的微观组织和高温抗氧化性能

刘洪喜; 赵艳爽; 张晓伟; 郝轩宏; 张璐璐

doi:10.3788/OPE.20192702.0316

您当前的位置：

首页 >

文章列表页 >

激光熔覆原位自生Ti-Al-Si复合涂层的微观组织和高温抗氧化性能

现代应用光学 | 更新时间：2020-08-13

- 激光熔覆原位自生Ti-Al-Si复合涂层的微观组织和高温抗氧化性能
- Microstructure and high-temperature oxidation resistance of laser cladding in-situ synthesis Ti-Al-Si composite coatings
- 光学精密工程 2019年27卷第2期页码：316-325
- 作者机构：
  
  昆明理工大学材料科学与工程学院，云南昆明 650093
- 作者简介：
  
  [ "刘洪喜(1972-)，男，湖北黄冈人，博士，教授，博士生导师，2003年、2007年于哈尔滨工业大学分别获得硕士、博士学位，主要从事离子束和激光束表面改性、功能涂层优化设计与制备、激光增材制造方面的研究。E-mail：piiiliuhx@sina.com" ]
- 基金信息：
  
  国家自然科学基金资助项目(11674134);云南省应用基础研究计划重点项目(2016FA020);云南省中青年学术技术带头人后备人才资助项目(2014HB007)
- DOI：10.3788/OPE.20192702.0316
  中图分类号： TN249; TB331
- 收稿日期：2018-08-21，
  
  录用日期：2018-10-8，
  
  纸质出版日期：2019-02-15
- 稿件说明：
移动端阅览
刘洪喜, 赵艳爽, 张晓伟, 等. 激光熔覆原位自生Ti-Al-Si复合涂层的微观组织和高温抗氧化性能[J]. 光学精密工程, 2019,27(2):316-325.

Hong-xi LIU, Yan-shuang ZHAO, Xiao-wei ZHANG, et al. Microstructure and high-temperature oxidation resistance of laser cladding in-situ synthesis Ti-Al-Si composite coatings[J]. Optics and precision engineering, 2019, 27(2): 316-325.
刘洪喜, 赵艳爽, 张晓伟, 等. 激光熔覆原位自生Ti-Al-Si复合涂层的微观组织和高温抗氧化性能[J]. 光学精密工程, 2019,27(2):316-325. DOI： 10.3788/OPE.20192702.0316.

Hong-xi LIU, Yan-shuang ZHAO, Xiao-wei ZHANG, et al. Microstructure and high-temperature oxidation resistance of laser cladding in-situ synthesis Ti-Al-Si composite coatings[J]. Optics and precision engineering, 2019, 27(2): 316-325. DOI： 10.3788/OPE.20192702.0316.

摘要

为提高钛合金的高温抗氧化性能，采用激光熔覆原位自生技术，在TC4钛合金表面自行设计并制备了原子百分比为Ti:Al:Si=41:41:18和Ti:Al:Si=35:35:30的两种涂层。通过XRD、OM、SEM表征了涂层的微观组织和物相组成；借助管式电阻炉测试了涂层和基体试样在800 ℃×24 h×5次循环氧化条件下的高温抗氧化性能；结合氧化增重和氧化动力学曲线分析了涂层的高温抗氧化机理。结果表明，涂层主要由Ti

、Ti

Al、TiAl和TiAl

等物相组成。涂层中没有出现一般激光熔覆所产生的外延生长柱状晶组织，全部为细小等轴晶。在800 ℃×24 h×5次循环氧化条件下，TC4基材单位面积的氧化增重约为35.1 mg·cm

-2

，涂层的约为2.8 mg·cm

-2

和3.3 mg·cm

-2

。两种涂层的高温抗氧化性能较钛合金基材分别提高了12.5倍和10.6倍。激光熔覆原位自生Ti-Al-Si复合涂层能明显改善TC4钛合金的高温抗氧化性能。涂层抗氧化性改善的机理，一方面是表面生成了连续致密的TiO

、Al

、SiO

氧化层，阻碍了氧扩散；另一方面是提高了氧化层的黏附性，使氧化层不易从涂层表面剥落，对涂层未氧化部分起到了很好的保护作用。

Abstract

To improve the high-temperature oxidation resistance of titanium alloys. Two kinds of Ti:Al:Si=41:41:18 (at.%) and Ti:Al:Si=35:35:30 (at.%) composite coatings were fabricated by laser cladding in-situ synthesis on TC4 titanium alloy. The microstructure and phase composition of the composite coatings were characterized by X-ray Diffraction (XRD)

Optical Microscopy (OM) and Scanning Electron Microscope (SEM). The oxidation resistance of the coatings and the substrate sample under 800 ℃×24 h×5 times cycle oxidation condition was tested by tube resistance furnace. The mechanism of high-temperature oxidation resistance was analyzed by oxidation kinetics curves and oxidation mass gain. The results show that the cladding coatings are mainly composed of Ti

TiAl and TiAl

phases

and there are no epitaxial columnar crystal structures as considered by a general laser cladding coating

all of which are fine equiaxed crystals. Under the condition of 800 ℃×24 h×5 times cycle oxidation

the weight gain per unit area of TC4 substrate is about 35.1 mg·cm

-2

and the laser cladding composite coatings are about 2.8 mg·cm

-2

and 3.3 mg·cm

-2

. The high-temperature oxidation resistance of the two kinds of coatings is 12.5 and 10.6 times higher than that of the titanium alloy substrate. The oxidation resistance of laser cladding in-situ synthesis Ti-Al-Si composite coatings has been significantly improved. On the one hand

the continuous dense TiO

and SiO

oxide layers have been obtained on the surface

which hinders the diffusion of oxygen and improves the oxidation behaviors. On the other hand

the adhesion of the oxide layer is improved so that the oxide layer is not easily peeled off from the coating surface and the non-oxidized portion of the coating is well protected.

关键词

Keywords

references

蔡建明, 弭光宝, 高帆, 等.航空发动机用先进高温钛合金材料技术研究与发展[J].材料工程, 2016, 44(8):1-10.

CAI J M, MI G B, GAO F, et al ..Research and development of some advanced high temperature titanium alloys for aero-engine[J]. Journal of Materials Engineering , 2016, 44(8):1-10.(in Chinese)

SINGH P, PUNGOTRA H, KALSI N S.On the characteristics of titanium alloys for the aircraft applications[J]. Materials Today:Proceedings , 2017, 4(8):8971-8982.

DAI J J, ZHU J Y, CHEN C Z, et al ..High temperature oxidation behavior and research status of modifications on improving high temperature oxidation resistance of titanium alloys and titanium aluminides:A review[J]. Journal of Alloys and Compounds , 2016, 685(11):784-798.

LIANG S X, YIN L X, LIU L X, et al ..Kinetics of thermodiffusion of TZ20 titanium alloy gas-nitride within temperature of 500℃-650℃[J]. Journal of Alloys and Compounds , 2018, 734(2):172-178.

SITEK R, BOLEK T, MIZERA J.Microstructure and properties of Ti-Al intermetallic/Al 2 O 3 layers produced on Ti 6 Al 2 Mo 2 Cr titanium alloy by PACVD method[J]. Applied Surface Science , 2018, 437(4):19-27.

KOSEKI S, INOUE K, SEKIYA K, et al ..Wear mechanisms of PVD-coated cutting tools during continuous turning of Ti 6 Al 4 V alloy[J]. Precision Engineering , 2017, 47(1):434-444.

FOMIN A, FOMINA M, KOSHURO V, et al ..Structure and mechanical properties of hydroxyapatite coatings produced on titanium using plasma spraying with induction preheating[J]. Ceramics International , 2017, 43(14):11189-11196.

GAO C, DAI L, MENG W, et al ..Electrochemically promoted electroless nickel-phosphorous plating on titanium substrate[J]. Applied Surface Science , 2017, 392(1):912-919.

刘洪喜, 李正学, 张晓伟, 等.热处理条件下激光原位合成高铌Ti-Al金属间化合物复合涂层的微结构特征[J].光学精密工程, 2017, 25(6):1477-1485.

LIU H X, LI ZH X, ZHANG X W, et al ..Microstructure characteristics of laser in situ synthesis high niobium Ti-Al intermetallic compound coating under heat treatment[J]. Opt.Precision Eng. , 2017, 25(6):1477-1485.(in Chinese)

YANG C Y, CHENG X, TANG H B, et al ..Influence of microstructures and wear behaviors of microalloyed coatings on TC11 alloy surface using laser cladding technique[J]. Surface&Coatings Technology , 2018, 337(3):97-103.

SADEQ F O, SHARIFITABAR M, AFARANI M S.Synthesis of Ti-Si-Al coatings on the surface of Ti 6 Al 4 V alloy via hot dip siliconizing route[J]. Surface&Coatings Technology , 2018, 337(3):349-356.

SHAHZAD A, ZADORAZHNYY V Y, PAVLOV M D, et al ..Deposition of the Ti-Al coatings on different metallic substrates by mechanical alloying and subsequent laser treatment[J]. Journal of Alloys and Compounds , 2018, 731(1):295-1302.

VALKOV S, PETROV P, LAZAROVA R, et al .Formation and characterization of Al-Ti-Nb alloys by electron-beam surface alloying[J]. Applied Surface Science , 2016, 389(12):768-774.

DAI J J, ZHANG F Y, WANG A M, et al ..Microstructure and properties of Ti-Al coating and Ti-Al-Si system coatings on Ti 6 Al 4 V fabricated by laser surface alloying[J]. Surface&Coatings Technology , 2017, 309(1):805-813.

CANDEL J J, JIMEMEZ J A, FRANCONETTI P.Effect of laser irradiation on failure mechanism of Ti-Al composite coating produced by laser cladding[J]. Journal of Materials Processing Technology , 2014, 214(11):2325-2332.

LIU H X, ZHANG X W, JIANG Y H, et al ..Microstructure and high temperature oxidation resistance of in-situ synthesized TiN/Ti 3 Al intermetallic composite coatings on Ti 6 Al 4 V alloy by laser cladding process[J]. Journal of Alloys and Compounds , 2016, 670(6):268-274.

MALIUTINA I N, MOHAND H S, SLJOBERT J, et al ..Structure and oxidation behavior of γ-TiAl coating produced by laser cladding on titanium alloy[J]. Surface&Coatings Technology , 2017, 319(6):136-144.

郭纯, 周建松, 陈建敏.钛合金表面激光熔覆原位自生制备Ti 5 Si 3 涂层结构及摩擦学性能[J].无机材料学报, 2012, 27(9):970-976.

GUO CH, ZHOU J S, CHEN J M.Microstructure and tribological properties of Ti 5 Si 3 coating in-situ synthesized on titanium substrate by laser cladding[J]. Journal of Inorganic Materials , 2012, 27(9):970-976.(in Chinese)

BROVA M J, ALAT E, PAULEY M A, et al ..Undoped and ytterbium doped titanium aluminum nitride coatings for improved oxidation behavior of nuclear fuel cladding[J]. Surface&Coatings Technology , 2017, 331(12):163-171.

赵宇光, 周伟, 彭新, 等.钛合金表面低氧压熔结Al-Cr涂层及其高温抗氧化性[J].吉林大学学报(工学版), 2004, 34(4):521-526.

ZHAO Y G, ZHOU W, PENG X, et al ..Low oxygen pressure self-fused Al-Cr coatings formed on surface of titanium alloy and their oxidation resistance[J]. Journal of Jinlin Univsrsity (Engineering and Technology Edition), 2004, 34(4):521-526.(in Chinese)

张红霞.钛合金表面激光熔覆陶瓷Ti-Al-Si复合涂层的组织结构与耐磨性[D].济南: 山东大学, 2016.

ZHANG H X. Investigation on Microstructures and Wear Resistance of Ceramics and Ti-Al-Si Composite Coating [D].Jinan: Shandong University, 2016.(in Chinese)

单晓浩, 王存山, 于群.钛合金表面激光熔覆Nb-Al-Ti高温合金涂层的组织与性能[J].中国激光, 2016, 45(8):184-191.

SHAN X H, WANG C SH, YU Q.Microstructure and property of Nb-Al-Ti high temperature alloy coating by laser cladding on Ti alloy surfaces[J]. Chinese Journal of Lasers , 2016, 45(8):184-191.(in Chinese)

陶俊.钛合金表面几种新型耐磨涂层激光制备、组织及性能初步研究[D].镇江: 江苏大学, 2014.

TAO J. Preliminary Study on Preparation, Microstructure and Properties of New Types of Wear Resistance Coating on Titanium Alloy Substrate by Laser [D].Zhenjiang: Jiangsu University, 2014.(in Chinese)

张晓伟, 刘洪喜, 蒋业华, 等.激光铝热还原法制备Al 2 O 3 /Ti-Al基复合涂层[J].无机材料学报, 2013, 28(9):1033-1039.

ZHANG X W, LIU H X, JIANG Y H, et al ..Microstructure of Al 2 O 3 /Ti-Al composite coatings prepared by laser aluminum thermal reduction processing[J]. Journal of Inorganic Materials , 2013, 28(9):1033-1039.(in Chinese)

刘洪喜, 李正学, 张晓伟, 等.热处理对钛合金表面激光原位合成高铌Ti-Al金属间化合物涂层高温抗氧化行为的影响[J].金属学报, 2017, 53(2):201-210.

LIU H X, LI ZH X, ZHANG X W, et al ..Effect of heat treatment on high-temperature oxidation resistance of high niobium Ti-Al intermetallic coating fabricated by laser in situ synthesis on titanium alloy[J]. Acta Metallurgica Sinica , 2017, 53(2):201-210.(in Chinese)

BRAUN R, FROHLICH M, BRAUE W, et al ..Oxidation behavior of gamma titanium aluminides with EB-PVD thermal barrier coatings exposed to air at 900℃[J]. Surface&Coating Technology , 2007, 202(3):676-680.

浏览量

133

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

热处理条件下激光原位合成高铌Ti-Al金属间化合物复合涂层的微结构特征

纳米Fe-Al/Cr3C2复合涂层的抗电化学腐蚀性能

纳米Fe-Al/Cr₃C₂复合涂层的抗电化学腐蚀性能

选区激光熔化成形W-Ni-Cu的成形工艺及热物理性能

纳米Fe-Al/Cr₃C₂复合涂层及其抗高温腐蚀性能