激发-发射荧光矩阵结合二阶校正方法检测湖水中多环芳烃

王忠东; 王玉田

doi:10.3788/OPE.20192710.2089

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激发-发射荧光矩阵结合二阶校正方法检测湖水中多环芳烃

现代应用光学 | 更新时间：2020-08-13

- 激发-发射荧光矩阵结合二阶校正方法检测湖水中多环芳烃
- Determination of polycyclic aromatic hydrocarbons in lake water using excitation-emission fluorescence matrix coupled with second-order calibration algorithm
- 光学精密工程 2019年27卷第10期页码：2089-2096
- 作者机构：
  
  1.广西科技师范学院，广西来宾 533000
  2.燕山大学河北省测试计量技术及仪器重点实验室，河北秦皇岛 066004
- 作者简介：
  
  [ "王忠东(1968-)，男，山东青州人，博士，教授，1991年于吉林工业大学获得学士学位，2000年于大庆石油学院获得硕士学位，2005年于燕山大学获得博士学位，主要从事光电检测及光谱分析方面的研究。E-mail：1647402833@qq.com" ]
  [ "王玉田(1952-)，男，辽宁本溪人，博士，教授，博士生导师，1977年、1981年、1995年于哈尔滨工业大学分别获得学士、硕士、博士学位，主要从事光电检测技术、环境检测仪器及工程、光纤传感技术的研究。E-mail：y.t.wang@163.com" ]
- 基金信息：
  
  国家自然科学基金资助项目(61471312)
- DOI：10.3788/OPE.20192710.2089
  中图分类号： O657.3; O621.22
- 收稿日期：2019-01-17，
  
  录用日期：2019-3-10，
  
  纸质出版日期：2019-10-15
- 稿件说明：
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王忠东, 王玉田. 激发-发射荧光矩阵结合二阶校正方法检测湖水中多环芳烃[J]. 光学精密工程, 2019,27(10):2089-2096.

Zhong-dong WANG, Yu-tian WANG. Determination of polycyclic aromatic hydrocarbons in lake water using excitation-emission fluorescence matrix coupled with second-order calibration algorithm[J]. Optics and precision engineering, 2019, 27(10): 2089-2096.
王忠东, 王玉田. 激发-发射荧光矩阵结合二阶校正方法检测湖水中多环芳烃[J]. 光学精密工程, 2019,27(10):2089-2096. DOI： 10.3788/OPE.20192710.2089.

Zhong-dong WANG, Yu-tian WANG. Determination of polycyclic aromatic hydrocarbons in lake water using excitation-emission fluorescence matrix coupled with second-order calibration algorithm[J]. Optics and precision engineering, 2019, 27(10): 2089-2096. DOI： 10.3788/OPE.20192710.2089.

摘要

多环芳烃广泛存在于大气、土壤和水环境中，对动植物和人类有着严重危害。为了快速检测水环境中的痕量多环芳烃(Polycyclic Aromatic Hydrocarbons，PAHs)，本文提出利用激发-发射荧光矩阵结合自加权交替归一残差拟合算法(Self-Weighted Alternating Normalized Residual Fitting Algorithm，SWANRF)检测湖水中的菲、蒽和荧蒽。与自加权交替三线性分解方法相比，SWANRF能够给出更满意的浓度预测结果，菲、蒽和荧蒽的平均回收率分别为(99.2±7.2)%，(101.7±7.7)%和(97.9±5.1)%；菲、蒽和荧蒽的预测均方根误差值分别为0.240，0.249和0.247 μg/L。实验结果表明，文章提出的方法能够实现未知干扰物共存的湖水中痕量多环芳烃的快速检测，且方法可靠。

Abstract

Polycyclic aromatic hydrocarbons (PAHs) widely exist in the atmosphere

soil

and water

and are severely harmful to animals

plants

and humans. Excitation-emission fluorescence matrix coupled with the self-weighted alternating normalized residue fitting algorithm (SWANRF) was proposed to determine the trace concentrations of PAHs phenanthrene

anthracene

and fluoranthene in lake water. Compared with the self-weighted alternating trilinear decomposition method

SWANRF provided more satisfactory concentration prediction results. The average recoveries of phenanthrene

anthracene

and fluoranthene are (99.2±7.2)%

(101.7±7.7)%

and (97.9±5.1)%

respectively. The predicted root mean square error values are 0.240 μg/L for phenanthrene

displacement 0.249 μg/L for anthracene

and 0.247 μg/L for fluoranthene. The experimental results demonstrate that the proposed method is reliable and can achieve simultaneous and rapid determination of trace PAHs in lake water with unknown interference.

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references

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